Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate

Base Information

• Chemical Name: Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate
• CAS No.: 35636-63-6
• Deprecated CAS: 63661-03-0
• Molecular Formula: C₂₁H₁₉N₅O₇
• Molecular Weight: 453.411
• European Community (EC) Number: 252-650-1
• DSSTox Substance ID: DTXSID10865783
• Nikkaji Number: J42.289D
• Mol file: 35636-63-6.mol

Synonyms:35636-63-6;EINECS 252-650-1;2-((2,5-Dicarbomethoxyphenyl)azo)-N-(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)-3-oxo-butanamide;dimethyl 2-[[1,3-dioxo-1-[(2-oxo-1,3-dihydrobenzimidazol-5-yl)amino]butan-2-yl]diazenyl]benzene-1,4-dicarboxylate;Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate;EC 252-650-1;1,4-Benzenedicarboxylic acid, 2-((1-(((2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino)carbonyl)-2-oxopropyl)azo)-, dimethyl ester;1,4-Benzenedicarboxylic acid, 2-(2-(1-(((2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino)carbonyl)-2-oxopropyl)diazenyl)-, 1,4-dimethyl ester;Dimethyl 2-((1-(((2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino)carbonyl)-2-oxopropyl)azo)terephthalate;1,4-Benzenedicarboxylic acid, 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]-, dimethyl ester;1,4-Benzenedicarboxylic acid, 2-[2-[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]diazenyl]-, 1,4-dimethyl ester;SCHEMBL22507;DTXSID10865783;A834678;W-110864;1,4-Benzenedicarboxylic acid, 2-[[1-[[(2,3-dihydro-2-oxo- 1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl ]azo]-, dimethyl ester;2-[1-(2-Oxo-2,3-dihydro-1H-benzimidazol-5-ylaminocarbonyl)acetonylazo]terephthalic acid dimethyl ester;dimethyl 2-[2-oxo-1-[(2-oxo-1,3-dihydrobenzimidazol-5-yl)carbamoyl]propyl]azobenzene-1,4-dicarboxylate;Imipenem

Chemical Property of Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate

Chemical Property:

• Vapor Pressure: 3.48E-14mmHg at 25°C
• Refractive Index: 1.665
• Boiling Point: 596.3 °C at 760 mmHg
• PKA: 1.15±0.59(Predicted)
• Flash Point: 314.4 °C
• PSA: 172.14000
• Density: 1.48 g/cm³
• LogP: 2.18240
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 9
• Exact Mass: 453.12844796
• Heavy Atom Count: 33
• Complexity: 832

Purity/Quality:

99.9% ^*data from raw suppliers

PIGMENT YELLOW 175 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)C(C(=O)NC1=CC2=C(C=C1)NC(=O)N2)N=NC3=C(C=CC(=C3)C(=O)OC)C(=O)OC

Technology Process of Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate

There total 1 articles about Dimethyl 2-[[1-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-oxopropyl]azo]terephthalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl aminoterephthalate hydrochloride + 5-Acetoacetyl-amino-benzimidazol-2-one (26576-46-5) → Pigment Yellow 175 (35636-63-6)

Guidance literature:

dimethyl aminoterephthalate hydrochloride; With sodium nitrite; at 0 - 10 ℃;

5-Acetoacetyl-amino-benzimidazol-2-one; at 20 - 95 ℃; Product distribution / selectivity; Aqueous acetate buffer;

upstream raw materials:

5-Acetoacetyl-amino-benzimidazol-2-one

Refernces