2-Methoxytetradecane

Base Information

• Chemical Name: 2-Methoxytetradecane
• CAS No.: 88959-02-8
• Molecular Formula: C15H32O
• Molecular Weight: 228.418
• DSSTox Substance ID: DTXSID40522978
• Mol file: 88959-02-8.mol

Synonyms:2-METHOXYTETRADECANE;88959-02-8;DTXSID40522978

Chemical Property of 2-Methoxytetradecane

Chemical Property:

• XLogP3: 6.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 228.245315640
• Heavy Atom Count: 16
• Complexity: 123

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCC(C)OC

Technology Process of 2-Methoxytetradecane

There total 3 articles about 2-Methoxytetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methanol (67-56-1) + tetradecan-2-yl phenyl selenide (89357-91-5) → 1-tetradecene (1120-36-1) + tetradec-2-ene (1652-97-7) + 2-methoxytetradecane (88959-02-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; Ambient temperature;

DOI:10.1039/c39830001501

Reference yield:

1-tetradecene (1120-36-1) → 2-hydroxytetradecanoic acid methyl ester (56009-40-6,149948-89-0) + 1-hydroxy-propane-1,2,3-tricarboxylic acid (320-77-4) + tetradecan-2-one (2345-27-9) + methyl tridecanoate (1731-88-0) + 2-methoxytetradecane (88959-02-8) + citric acid (77-92-9,906507-37-7)

Guidance literature:

With oxygen; at 30 ℃; for 72h; Product distribution; oxidation and methylation, Candida lipolytica IFO 0746 or Candida tropicalis IFO 0589, rate of oxygen uptake; other time;

Reference yield:

methanol (67-56-1) + tetradecan-2-yl phenyl selenide (89357-91-5) → 1-tetradecene (1120-36-1) + trans-2-tetradecene (35953-54-9) + 2-methoxytetradecane (88959-02-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; at 25 ℃; for 1h; Yields of byproduct given;

upstream raw materials:

methanol

tetradecan-2-yl phenyl selenide

1-tetradecene

Refernces

• 1、 Uemura, Sakae,Fukuzawa, Shin-ichi,Toshimitsu, Akio. "A Novel, Simple Method for Transformation of C-Se to C-O Bonds". . p. 1501 - 1502. Retrieved 2007/10/02.