Benzeneethanol, b-(1-methylethoxy)-, (S)-

Base Information

• Chemical Name: Benzeneethanol, b-(1-methylethoxy)-, (S)-
• CAS No.: 89101-31-5
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol file: 89101-31-5.mol

Synonyms:

Chemical Property of Benzeneethanol, b-(1-methylethoxy)-, (S)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzeneethanol, b-(1-methylethoxy)-, (S)-

There total 21 articles about Benzeneethanol, b-(1-methylethoxy)-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

styrene oxide (96-09-3) + isopropyl alcohol (67-63-0,8013-70-5) → 2-isopropoxy-2-phenylethanol (89101-31-5,90332-91-5)

Guidance literature:

With erbium(III) triflate; at 25 ℃; for 1.5h;

DOI:10.1055/s-0029-1216956

Reference yield: 97.0%

isopropyl alcohol (67-63-0,8013-70-5) + 2‐phenyloxirane → 2-isopropoxy-2-phenylethanol (89101-31-5,90332-91-5)

Guidance literature:

With sulfuric acid; silica gel; at 20 ℃; for 0.0833333h;

DOI:10.1080/10426500490459722

Reference yield: 90.0%

styrene oxide (96-09-3) + isopropyl alcohol (67-63-0,8013-70-5) → 2-isopropoxy-2-phenylethanol (89101-31-5,90332-91-5) + 2-isopropoxy-1-phenylethanol (3578-32-3)

Guidance literature:

With zirconium tetrakis(dodecyl sulfate); for 0.25h; Reflux;

DOI:10.1002/hlca.200900239

upstream raw materials:

styrene oxide

isopropyl alcohol

titanium(IV)isopropoxide

isopropyl titanoate(IV)

Downstream raw materials:

C₂₆H₃₃BrN₂O₅S

methyl-2-[5-methyl-6-(1,3-oxazol-2-yl)-2,4-dioxo-1-[(2S)-2-phenyl-2-(propan-2-yloxy)ethyl]-1H,2H,3H,4H-thieno[2,3-d]pyrimidin-3-yl]propanoic acid

C₂₂H₂₅BrN₂O₅S

Refernces

• 1、 Rahmatpour, Ali,Sajjadinezhad, Seyed Mehrzad. "Cross-linked poly(N-vinylpyrrolidone)-titanium tetrachloride complex: A novel stable solid TiCl4 equivalent as a recyclable polymeric Lewis acid catalyst for regioselective ring-opening alcoholysis of epoxides". . . Retrieved 2021/08/09.
• 2、 Bohigues, Benjamin,Boronat, Mercedes,Corma, Avelino,Lopes, Christian W.,Meira, Débora M.,Moliner, Manuel,Rojas-Buzo, Sergio. "Tailoring Lewis/Br?nsted acid properties of MOF nodesviahydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications". . p. 10106 - 10115. Retrieved 2021/08/04.