Thiocarbonyl selenide

Base Information

• Chemical Name: Thiocarbonyl selenide
• CAS No.: 5951-19-9
• Molecular Formula: CSSe
• Molecular Weight: 123.037
• DSSTox Substance ID: DTXSID90208210
• Nikkaji Number: J96.041A
• Wikidata: Q83082311
• Mol file: 5951-19-9.mol

Synonyms:Thiocarbonyl selenide;Carbo selenide;5951-19-9;Carbon sulfide selenide;Carbon sulfide,selenide;Selenoxo(thioxo)methane #;DTXSID90208210;UGVGOQWEDNFDPF-UHFFFAOYSA-N

Chemical Property of Thiocarbonyl selenide

Chemical Property:

• Vapor Pressure: 82.2mmHg at 25°C
• Boiling Point: 84°Cat760mmHg
• Flash Point: 4.6°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 123.88859
• Heavy Atom Count: 3
• Complexity: 27.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(=S)=[Se]

Technology Process of Thiocarbonyl selenide

There total 4 articles about Thiocarbonyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + selenium (7782-49-2) → carbon monosulfide (2944-05-0,767590-23-8) + carbon selenide sulfide (5951-19-9)

Guidance literature:

Electric Arc; 0.1 torr;

Reference yield:

tetrachloromethane (56-23-5) + selenium (7782-49-2) → 1,1,2,2-tetrachloroethylene (127-18-4) + carbon selenide sulfide (5951-19-9) + carbon diselenide (506-80-9) + hexachloroethane (67-72-1) + selenophosgene (80008-70-4)

Guidance literature:

In neat (no solvent); decomposition of CCl4 in the presence of Se (with impurities of S) at 250°C; further products;; determination by IR;;

DOI:10.1016/S0040-4039(00)90737-8 DOI:10.1016/S0040-4039(01)89584-8

Reference yield:

selenium (7782-49-2) + pyrographite (7440-44-0) → carbon selenide sulfide (5951-19-9) + carbon diselenide (506-80-9)

Guidance literature:

In carbon disulfide; electric powdering of a Se-C-electrode;;

upstream raw materials:

carbon disulfide

selenium

tetrachloromethane

pyrographite

Downstream raw materials:

selenium tetrabromide

carbon tetrabromide

(PPh3)2Pd(η2-CSSe)

Sn(C₆H₂(CH(Si(CH₃)3)2)3)(C₆H₂(CH(CH₃)2)3)S₂CSe

Refernces