Technology Process of Ethanol, 2-[2-[2-(2-phenoxyethoxy)ethoxy]ethoxy]-, benzoate
There total 10 articles about Ethanol, 2-[2-[2-(2-phenoxyethoxy)ethoxy]ethoxy]-, benzoate which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1: 52 percent / potassium tert-butoxide / tetrahydrofuran / 13 h / Heating
2: 89 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature
3: 81 percent / toluene / 12 h / Heating
4: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr
5: 72 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature
6: 90 percent / H2 / 10percent Pd/C / ethanol / 8 h / 2585.7 Torr
7: 48percent HBF4, NaNO2 / H2O / 0.17 h / 0 °C
8: NaOAc / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 24 h
With
pyridine; hydrogenchloride; tetrafluoroboric acid; potassium tert-butylate; hydrogen; sodium acetate; sodium nitrite;
palladium on activated charcoal;
In
tetrahydrofuran; ethanol; dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; water; toluene;
DOI:10.1021/jo00183a021
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 81 percent / toluene / 12 h / Heating
2: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr
3: 72 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature
4: 90 percent / H2 / 10percent Pd/C / ethanol / 8 h / 2585.7 Torr
5: 48percent HBF4, NaNO2 / H2O / 0.17 h / 0 °C
6: NaOAc / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 24 h
With
pyridine; hydrogenchloride; tetrafluoroboric acid; hydrogen; sodium acetate; sodium nitrite;
palladium on activated charcoal;
In
ethanol; dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; water; toluene;
DOI:10.1021/jo00183a021
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 81 percent / toluene / 12 h / Heating
2: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr
3: 72 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature
4: 90 percent / H2 / 10percent Pd/C / ethanol / 8 h / 2585.7 Torr
5: 48percent HBF4, NaNO2 / H2O / 0.17 h / 0 °C
6: NaOAc / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 24 h
With
pyridine; hydrogenchloride; tetrafluoroboric acid; hydrogen; sodium acetate; sodium nitrite;
palladium on activated charcoal;
In
ethanol; dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; water; toluene;
DOI:10.1021/jo00183a021