Zinc,[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-, (T-4)-

Base Information

• Chemical Name: Zinc,[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-, (T-4)-
• CAS No.: 14167-22-7
• Molecular Formula: C16H14 N2 O2 Zn
• Molecular Weight: 331.689
• Mol file: 14167-22-7.mol

Synonyms:Zinc,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-,(T-4)-; Zinc, [[a,a'-(ethylenedinitrilo)di-o-cresolato](2-)]-(7CI,8CI); o-Cresol, a,a'-(ethylenedinitrilo)di-, Zncomplex (6CI); (Bis(salicylidene)ethylenediaminato)zinc;N,N'-Ethylenebis(salicylaldiminato)zinc; NSC 872; [N,N'-Bis(salicylidene)ethylenediaminato]zinc

Chemical Property of Zinc,[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-, (T-4)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Zinc,[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-, (T-4)-

There total 1 articles about Zinc,[[2,2'-[1,2-ethanediylbis[(nitrilo-kN)methylidyne]]bis[phenolato-kO]](2-)]-, (T-4)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(2-Hydroxy-phenyl)-3-aza-1-amino-3-butene (19092-51-4) + zinc diacetate (557-34-6) → Zn(salen) (14167-22-7)

Guidance literature:

Reference yield:

Zn(salen) (14167-22-7) → N,N'-ethylenebis(salicylideneimine) (94-93-9)

Guidance literature:

With adenosine diphosphate tetrabutylammonium salt; In dimethylsulfoxide-d6;

DOI:10.1039/c5cc07413d

Reference yield:

Zn(salen) (14167-22-7) → salicylaldehyde (90-02-8)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium pyrophosphate / dimethyl sulfoxide / pH 7.4

2: water / dimethyl sulfoxide / 0.5 h / pH 7.4

With sodium pyrophosphate; water; In dimethyl sulfoxide;

DOI:10.1002/zaac.202000045

upstream raw materials:

4-(2-Hydroxy-phenyl)-3-aza-1-amino-3-butene

zinc diacetate

Downstream raw materials:

N,N'-ethylenebis(salicylideneimine)

salicylaldehyde

Refernces