1-azidooctane

Base Information

• Chemical Name: 1-azidooctane
• CAS No.: 7438-05-3
• Molecular Formula: C8H17N3
• Molecular Weight: 155.243
• Mol file: 7438-05-3.mol

Synonyms:

Chemical Property of 1-azidooctane

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-azidooctane

There total 5 articles about 1-azidooctane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-octyl methanesulfonate (16156-52-8) → di-n-octyl ether (629-82-3) + potassium mesylate (2386-56-3) + 1-azidooctane (7438-05-3)

Guidance literature:

With potassium azide; perhydrodibenzo-18-crown-6; In potassium hydroxide; chlorobenzene; at 60 ℃; for 1h;

DOI:10.1021/ja00322a030

Reference yield:

1-Iodooctane (629-27-6) → caprylnitrile (124-12-9) + Octanal (124-13-0) + 1-azidooctane (7438-05-3)

Guidance literature:

With tetrabutylammoniun azide; In toluene; at 80 ℃; for 24h; under 760.051 Torr;

DOI:10.1021/jo2004956

Reference yield:

n-octyl methanesulfonate (16156-52-8) → potassium mesylate (2386-56-3) + 1-azidooctane (7438-05-3)

Guidance literature:

With potassium azide; (C₈H₁₇)4N⁽¹⁺⁾*N₃^(1-); In sodium hydroxide; chlorobenzene; at 35 ℃; Rate constant;

DOI:10.1021/jo00133a006

upstream raw materials:

n-octyl methanesulfonate

1-Iodooctane

Downstream raw materials:

N-octylaniline

n-Octylamine

N-octylphthalimide

n-dioctylamine

Refernces

• 1、 Betti, Cecilia,Landini, Dario,Maia, Angelamaria. "Reactivity of anionic nucleophiles in ionic liquids and molecular solvents". . p. 1689 - 1695. Retrieved 2008/09/18.
• 2、 Landini, Dario,Maia, Angelamaria,Montanari, Fernando. "Phase-Transfer Reactions Catalyzed by Lipophilic Cryptands and Dicyclohexano-18-crown-6: Dehydrating Effect of Concentrated Aqueous Alkaline Solutions". . p. 2917 - 2923. Retrieved 2007/10/02.