ethyl N-[(E)-[(2E)-2-(ethoxycarbonylhydrazinylidene)ethylidene]amino]carbamate

Base Information

• Chemical Name: ethyl N-[(E)-[(2E)-2-(ethoxycarbonylhydrazinylidene)ethylidene]amino]carbamate
• CAS No.: 80805-23-8
• Molecular Formula: C8H14 N4 O4
• Molecular Weight: 230.2212
• NSC Number: 135288
• Mol file: 80805-23-8.mol

Synonyms:NSC135288;NSC-135288;80805-23-8

Chemical Property of ethyl N-[(E)-[(2E)-2-(ethoxycarbonylhydrazinylidene)ethylidene]amino]carbamate

Chemical Property:

• Density: 1.237g/cm³
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 7
• Exact Mass: 230.10150494
• Heavy Atom Count: 16
• Complexity: 249

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)NN=CC=NNC(=O)OCC
• Isomeric SMILES: CCOC(=O)N/N=C/C=N/NC(=O)OCC

Technology Process of ethyl N-[(E)-[(2E)-2-(ethoxycarbonylhydrazinylidene)ethylidene]amino]carbamate

There total 3 articles about ethyl N-[(E)-[(2E)-2-(ethoxycarbonylhydrazinylidene)ethylidene]amino]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Glyoxal (131543-46-9,107-22-2) + ethylhydrazine carboxylate (4114-31-2) → glyoxal-bis-ethoxycarbonylhydrazone (80805-23-8)

Guidance literature:

With acetic acid; In methanol; water;

DOI:10.1021/je00028a036

Reference yield: 76.0%

glyoxal sodium bisulfite (517-21-5) + ethylhydrazine carboxylate (4114-31-2) → glyoxal-bis-ethoxycarbonylhydrazone (80805-23-8)

Guidance literature:

With acetic acid; In water; for 18h; Ambient temperature;

DOI:10.1021/je00028a036

Reference yield:

glyoxal sodium bisulfite (517-21-5) → glyoxal-bis-ethoxycarbonylhydrazone (80805-23-8)

Guidance literature:

With water; beim Erwaermen;

DOI:10.1177/109442802237116

upstream raw materials:

Glyoxal

ethylhydrazine carboxylate

glyoxal sodium bisulfite

Refernces