Tetrafluorophenylphosphorane

Base Information

• Chemical Name: Tetrafluorophenylphosphorane
• CAS No.: 666-23-9
• Molecular Formula: C6H5 F4 P
• Molecular Weight: 184.073
• European Community (EC) Number: 211-562-3
• UNII: BW3P7JEA3G
• DSSTox Substance ID: DTXSID60216766
• Nikkaji Number: J205.963K
• Wikidata: Q83093061
• Mol file: 666-23-9.mol

Synonyms:Phenyltetrafluorophosphorane;Tetrafluorophenylphosphorane;666-23-9;BW3P7JEA3G;EINECS 211-562-3;UNII-BW3P7JEA3G;C6H5F4P;Tetrafluoro(phenyl)phosphorane;Phosphorane, tetrafluorophenyl-;SCHEMBL2966242;DTXSID60216766;C6-H5-F4-P;TETRAFLUORO(PHENYL)-.LAMBDA.5-PHOSPHANE

Chemical Property of Tetrafluorophenylphosphorane

Chemical Property:

• PSA: 13.59000
• LogP: 3.40320
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 184.00649981
• Heavy Atom Count: 11
• Complexity: 135

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(F)(F)(F)F

Technology Process of Tetrafluorophenylphosphorane

There total 6 articles about Tetrafluorophenylphosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

potassium pentafluoro(phenyl)-λ6-phosphate → phenyltetrafluorophosphorane (666-23-9)

Guidance literature:

With chloro-trimethyl-silane; In acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.202010943

Reference yield:

tetraphenyltin(IV) (595-90-4) + phosphorus pentafluoride (7647-19-0,874483-74-6) → phenyltetrafluorophosphorane (666-23-9) + triphenyltinfluoride (379-52-2)

Guidance literature:

135°C;

Reference yield:

Dichlorophenylphosphine (644-97-3) → phenyltetrafluorophosphorane (666-23-9)

Guidance literature:

With antimony(III) fluoride;

upstream raw materials:

phenyltetrachlorophosphorane

Dichlorophenylphosphine

phenyldifluorophosphine

tetraphenyltin(IV)

Downstream raw materials:

C₇H₈F₃OP

Phenylphosphonsaeure-methylester-fluorid

Dimethylamino-trifluor-phenyl-phosphoran

C₈H₁₀F₃OP

Refernces

• 1、 Schmutzler, Reinhard,Heuer, Lutz,Schomburg, Dietmar. "TRANSFORMATIONS OF DIFLUOROPHOSPHINES: THE INFLUENCE OF SOLVENT ON THE REACTION PATHWAY AND RING SIZE IN CYCLOPOLYPHOSPHINES". . p. 149 - 156. Retrieved 2007/10/02.
• 2、 Frohn, H. J.,Maurer, H.. "BEITRAEGE ZUR CHEMIE DES IODOPENTAFLUORIDS. TEIL IV. IF5 EIN SELEKTIVES OXIDATIVES FLUORIERUNGSMITTEL FUER ORGANOPHOSPHOR(III)-VERBINDUNGEN". . p. 73 - 82. Retrieved 2007/10/02.