Phosphinecarbothioamide, 1,1-dicyclohexyl-N-phenyl-

Base Information

• Chemical Name: Phosphinecarbothioamide, 1,1-dicyclohexyl-N-phenyl-
• CAS No.: 899-27-4
• Molecular Formula: C19H28NPS
• Molecular Weight: 333.478
• Mol file: 899-27-4.mol

Synonyms:

Chemical Property of Phosphinecarbothioamide, 1,1-dicyclohexyl-N-phenyl-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphinecarbothioamide, 1,1-dicyclohexyl-N-phenyl-

There total 1 articles about Phosphinecarbothioamide, 1,1-dicyclohexyl-N-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 1-(dicyclohexylphosphino)-N-phenylthioformamide (899-27-4)

Guidance literature:

(C6H11)2PH, PhNCS (ohne Lsm.);

Reference yield: 84.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 1-(dicyclohexylphosphino)-N-phenylthioformamide (899-27-4) → [Au((C6H11)2PC(S)NC6H5)]2 (215436-87-6)

Guidance literature:

With Et₃N; In tetrahydrofuran; N2-atmosphere; addn. of 1.1 equiv. of phosphine to Au-complex, dropwise addn. of Et3N, stirring for 45 min; filtration, solvent removal (vac.), washing (EtOH), recrystn. (CH2Cl2/EtOH=4:1);

DOI:10.1016/S0020-1693(98)00144-3

Reference yield: 80.0%

gold(III) tetrachloride trihydrate + 1-(dicyclohexylphosphino)-N-phenylthioformamide (899-27-4) → [Au((C6H11)2PC(S)NC6H5)]2 (215436-87-6)

Guidance literature:

With thiodiglycol; In ethanol; water; acetone; N2-atmosphere; dropwise addn. of 3 equiv. of thiodiglycol to HAuCl4 (in Me2CO/H2O=4:1) at 0°C during 2 h, dropwise addn. of 1 equiv. of phosphine (in EtOH, pptn.); filtration, washing (cold EtOH), recrystn. (CHCl3/EtOH=4:1), drying (vac., over P2O5); elem. anal.;

DOI:10.1016/S0020-1693(98)00144-3

Downstream raw materials:

{dicyclohexylphosphino-N-phenyl(thioformamido)}triphenyltin

trans-bis(dicyclohexylphosphino-N-phenyl(thioformamido))platinum(II)

HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅)2

(HgBr₂((C₆H₁₁)2PC(S)N(H)C₆H₅))2