Bis(p-chlorobenzylidene)ethylenediamine

Base Information

• Chemical Name: Bis(p-chlorobenzylidene)ethylenediamine
• CAS No.: 60434-95-9
• Molecular Formula: C16H14 Cl2 N2
• Molecular Weight: 305.207
• Hs Code.: 2921590090
• European Community (EC) Number: 667-293-0
• NSC Number: 12830
• Nikkaji Number: J734.206C
• Mol file: 60434-95-9.mol

Synonyms:60434-95-9;Bis(p-chlorobenzylidene)-ethylenediamine;Bis(p-chlorobenzylidene)ethylenediamine;1-(4-chlorophenyl)-N-[2-[(4-chlorophenyl)methylideneamino]ethyl]methanimine;Bis(p-chlorobenzylidene)ethylene diamine;N,N'-[4-Chlorobenzal]-1,2-diaminoethane;NSC12830;SCHEMBL10949573;VMWYCJFPSDIEJB-AYKLPDECSA-N;MFCD00018782;NSC-12830;AKOS015850318;FT-0623081;BIS-(P-CHLOROBENZYLIDENE)-ETHYLENEDIAMINE;1,2-Ethanediamine, N,N'-bis(4-chlorobenzylidene)-;N,N'-BIS(4-CHLOROBENZYLIDENE)ETHYLENEDIAMINE;(N1E,N2E)-N1,N2-bis(4-chlorobenzylidene)ethane-1,2-diamine;(1e,1'e)-N,N'-(ethane-1,2-diyl)bis(1-(4-chlorophenyl) methanimine)

Chemical Property of Bis(p-chlorobenzylidene)ethylenediamine

Chemical Property:

• Vapor Pressure: 7.33E-07mmHg at 25°C
• Boiling Point: 419.6°C at 760 mmHg
• Flash Point: 207.5°C
• PSA: 24.72000
• Density: 1.16g/cm³
• LogP: 4.53140
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 304.0534038
• Heavy Atom Count: 20
• Complexity: 282

Purity/Quality:

98%Min ^*data from raw suppliers

Bis(p-chlorobenzylidene)ethylenediamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C=NCCN=CC2=CC=C(C=C2)Cl)Cl

Technology Process of Bis(p-chlorobenzylidene)ethylenediamine

There total 5 articles about Bis(p-chlorobenzylidene)ethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

N-β-aminoethylcarbamic acid (109-58-0) + 4-chlorobenzaldehyde (104-88-1) → N,N'-bis(4-chlorobenzylidene)ethane-1,2-diamine (60434-95-9)

Guidance literature:

at 50 ℃;

DOI:10.1002/adsc.201200907

Reference yield: 96.0%

4-chlorobenzaldehyde (104-88-1) + ethylenediamine (107-15-3,85404-18-8) → N,N'-bis(4-chlorobenzylidene)ethane-1,2-diamine (60434-95-9)

Guidance literature:

for 0.0833333h; microwave irradiation;

DOI:10.1081/SCC-120023441

Reference yield: 89.2%

4-chlorobenzaldehyde (104-88-1) + ethylenediamine (107-15-3,85404-18-8) → (1E,1'E)-N,N'-(ethane-1,2-diyl)bis(1-(4-chlorophenyl)methanimine) (60434-95-9)

Guidance literature:

With potassium acetate; In ethanol; water; for 1h; Reflux;

DOI:10.14233/ajchem.2013.12108b

upstream raw materials:

4-chlorobenzaldehyde

ethylenediamine

3,4-dihydro-1,2,5-thiadiazole

N-β-aminoethylcarbamic acid

Downstream raw materials:

2-[1,3-bis-(4-chloro-benzyl)-imidazolidin-2-yl]-phenol

Re(CO)3Cl(N,N'-(4-chlorobenzaldehyde)-1,2-diiminoethane)

N,N'-bis-(4-chloro-benzyl)-ethylenediamine; dihydrochloride

trans-2,3-bis(4-chlorophenyl)piperazine

Refernces

• 1、 Ghaedi, Mehrorang,Noormohamadi, Hamid Reza,Asfaram, Arash,Montazerozohori, Morteza,Tashkhourian, Javad,Soylak, Mustafa. "Modification of platinum nanoparticles loaded on activated carbon and activated carbon with a new chelating agent for solid phase extraction of some metal ions". . p. 748 - 754. Retrieved 2016.
• 2、 F?ldesi, Tamás,Sipos, Gellért,Adamik, Réka,Nagy, Bálint,Tóth, Balázs L.,Bényei, Attila,Szekeres, Krisztina J.,Láng, Gyz G.,Demeter, Attila,Peelen, Timothy J.,Novák, Zoltán. "Design and application of diimine-based copper(i) complexes in photoredox catalysis". supporting information. p. 8343 - 8347. Retrieved 2019/09/30.
• 3、 Balinge, Kamlesh Rudreshwar,Khiratkar, Avinash Ganesh,Muskawar, Prashant Narayan,Thenmozhi,Bhagat, Pundlik Rambhau. "Facile access to polymer supported zinc–salen complex: highly efficient heterogeneous catalyst for synthesizing hydantoins, thiohydantoins and Schiff bases in aqueous medium". . p. 2075 - 2097. Retrieved 2017/12/26.