Bis(phenylethyl) disulfide

Base Information

• Chemical Name: Bis(phenylethyl) disulfide
• CAS No.: 52053-61-9
• Molecular Formula: C16H18S2
• Molecular Weight: 274.451
• NSC Number: 94793
• DSSTox Substance ID: DTXSID90294153
• Mol file: 52053-61-9.mol

Synonyms:bis(phenylethyl) disulfide

Chemical Property of Bis(phenylethyl) disulfide

Chemical Property:

• Boiling Point: 373.9°Cat760mmHg
• Flash Point: 186.7°C
• Density: 1.118g/cm³
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 274.08499292
• Heavy Atom Count: 18
• Complexity: 193

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C1=CC=CC=C1)SSC(C)C2=CC=CC=C2

Technology Process of Bis(phenylethyl) disulfide

There total 21 articles about Bis(phenylethyl) disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

C8H9O3S2(1-)*Na(1+) → di(α-methylbenzyl)disulfide (52053-61-9)

Guidance literature:

With 1H-imidazole; water; at 70 ℃; for 0.583333h; Green chemistry;

DOI:10.1080/10426507.2014.1003643

Reference yield: 47.0%

ethylbenzene (100-41-4,27536-89-6) → di(α-methylbenzyl)disulfide (52053-61-9)

Guidance literature:

With sulfur; In acetonitrile; at 50 ℃; for 24h; Irradiation; Inert atmosphere;

DOI:10.1039/c8sc00745d

Reference yield: 47.0%

→ di(α-methylbenzyl)disulfide (52053-61-9)

Guidance literature:

With sulfur; In acetonitrile; at 50 ℃; for 24h; under 0.0750075 Torr; Inert atmosphere; Irradiation;

upstream raw materials:

n-butyllithium

[(methylthio)methyl]-benzene

carbon dioxide

(+-)-methyl-(1-phenyl-ethyl)-sulfide

Downstream raw materials:

styrene

ethylbenzene

hydrogen sulfide

α-phenylethanesulfonic acid

Refernces

• 1、 -. "PHOTOCATALYTIC SYSTEM AND APPLICATIONS THEREOF". Page/Page column 27; 28. . Retrieved 2019/05/15.
• 2、 Savateev, Aleksandr,Kurpil, Bogdan,Mishchenko, Artem,Zhang, Guigang,Antonietti, Markus. "A waiting carbon nitride radical anion: A charge storage material and key intermediate in direct C-H thiolation of methylarenes using elemental sulfur as the s -source". . p. 3584 - 3591. Retrieved 2018/04/12.