N,N,2-TRIMETHYLPROPENYLAMINE

Base Information

• Chemical Name: N,N,2-TRIMETHYLPROPENYLAMINE
• CAS No.: 6906-32-7
• Molecular Formula: C6H13 N
• Molecular Weight: 99.1759
• Hs Code.: 2921199090
• Mol file: 6906-32-7.mol

Synonyms:Propenylamine,N,N,2-trimethyl- (6CI,7CI,8CI); 1-Dimethylamino-2-methyl-1-propene;N,N,2-Trimethylpropenylamine; N,N-Dimethylaminoisobutene;N,N-Dimethylisobutenylamine; NSC 521602; NSC 93894

Chemical Property of N,N,2-TRIMETHYLPROPENYLAMINE

Chemical Property:

• Vapor Pressure: 21.2mmHg at 25°C
• Boiling Point: 113°C at 760 mmHg
• Flash Point: 13.2°C
• PSA: 3.24000
• Density: 0.773g/cm³
• LogP: 1.47170

Purity/Quality:

99%, ^*data from raw suppliers

N,N-DIMETHYLISOBUTENYLAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N,2-TRIMETHYLPROPENYLAMINE

There total 8 articles about N,N,2-TRIMETHYLPROPENYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

2-isopropyl-3-methyl-1,3-oxazolidine (51439-17-9,162897-66-7) → N,N,2-Trimethyl-1-propen-1-amin (6906-32-7) + 2-isopropyl-1-methylazirine (132141-30-1)

Guidance literature:

at 600 ℃; under 0.005 - 0.01 Torr; flash vacuum thermolysis;

DOI:10.1016/S0040-4039(00)98017-1

Reference yield: 30.0%

dimethyl amine (124-40-3) + isobutyraldehyde (78-84-2) → N,N,2-Trimethyl-1-propen-1-amin (6906-32-7)

Guidance literature:

With sodium sulfate; In diethyl ether; at 0 ℃; for 0.333333h; Molecular sieve;

DOI:10.1002/chem.201503355

Reference yield:

N,N,2-trimethylpropionamide (21678-37-5) → N,N-dimethylisobutylamine (7239-24-9) + N,N,2-Trimethyl-1-propen-1-amin (6906-32-7)

Guidance literature:

With triethylammonium tetrakis(pentafluorophenyl)-borate; H₂SiEt₂; (2,6-bis(di-tert-butylphosphinito)phenyl)Ir(H)(SiEt₂H); (2,6-bis(di-tert-butylphosphinito)phenyl)Ir(H)3(SiEt₂H); hydrogen; In benzene-d6; at 60 ℃; for 0.4h; under 760.051 Torr;

DOI:10.1021/ja209567m

upstream raw materials:

dimethyl amine

isobutyraldehyde

N,N-dimethyl-2-methylprop-2-enylamine

(E)-1-N,N-dimethylamino-1-propene

Downstream raw materials:

Bis-(1-dimethylamino-2.2-dimethyl-cyclobutyl)-sulfon

(2-ethyl-4,4-dimethyl-2-nitro-cyclobutyl)-dimethyl-amine

methyl 2-(dimethylamino)-3,3-dimethylcyclobutane-carboxylate

Dimethyl-1-(dimethylamino)-2-methylpropylphosphonat

Refernces

• 1、 Park, Sehoon,Brookhart, Maurice. "Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines". experimental part. p. 640 - 653. Retrieved 2012/03/13.
• 2、 Bureau, R.,Mortier, J.,Joucla, M.. "Formation of azomethine ylids by thermolysis of oxazolidines. Study of the reaction in solution and in the gaseous phase". . p. 584 - 596. Retrieved 2007/10/02.