1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane

Base Information

• Chemical Name: 1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane
• CAS No.: 941-15-1
• Molecular Formula: C10H17ClSi2
• Molecular Weight: 228.869
• DSSTox Substance ID: DTXSID00499874
• Nikkaji Number: J1.868.809C
• Wikidata: Q82351071
• Mol file: 941-15-1.mol

Synonyms:1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane;941-15-1;DTXSID00499874;1-chloro-2-phenyltetramethyldisilane

Chemical Property of 1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 228.0557313
• Heavy Atom Count: 13
• Complexity: 172

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C1=CC=CC=C1)[Si](C)(C)Cl

Technology Process of 1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane

There total 7 articles about 1-Chloro-1,1,2,2-tetramethyl-2-phenyldisilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1,1,2,2-tetramethyl-2-phenyldisilane (35107-79-0) → 1-chloro-2-phenyltetramethyldisilane (941-15-1)

Guidance literature:

With trichloroisocyanuric acid; In tetrahydrofuran; at -20 - 20 ℃;

DOI:10.1002/chem.202104318

Reference yield: 62.0%

1,2-dichlorotetramethylsilane (4342-61-4) + phenylmagnesium bromide (100-58-3) → 1-chloro-2-phenyltetramethyldisilane (941-15-1)

Guidance literature:

In diethyl ether; at 0 ℃; for 8h; Inert atmosphere;

DOI:10.1002/asia.201402595

Reference yield: 53.0%

1,2-dichlorotetramethylsilane (4342-61-4) + phenyllithium (591-51-5) → 1-chloro-2-phenyltetramethyldisilane (941-15-1)

Guidance literature:

In dibutyl ether; at 0 - 20 ℃; for 18h;

DOI:10.1039/c9cc09851h

upstream raw materials:

(N,N-diethylamino)dimethylchlorosilane

dimethyl(phenyl)silyllithium

1,2-dichlorotetramethylsilane

phenylmagnesium bromide

Downstream raw materials:

1-Methoxymethyl-1,1,2,2-tetramethyl-2-phenyl-disilane

tetramethyl-1-phenyl-2-p-tolyldisilane

1-Bromomethyl-1,1,2,2-tetramethyl-2-phenyl-disilane

{[1-(Methoxy-dimethyl-silanyl)-vinyl]-dimethyl-silanyl}-benzene

Refernces

• 1、 Müller, Thomas,Nimoth, Jelte P.. "Hydrogen-Bridged Oligosilanylsilyl Mono- and Oligosilanylsilyl Dications". supporting information. . Retrieved 2022/01/08.
• 2、 He, Tao,Liu, Li-Chuan,Guo, Le,Li, Bin,Zhang, Qing-Wei,He, Wei. "Rhodium-Catalyzed Intermolecular trans-Disilylation of Alkynones with Unactivated Disilanes". supporting information. p. 10868 - 10872. Retrieved 2018/07/31.