Butane, 1-(1-methylpropoxy)-

Base Information

• Chemical Name: Butane, 1-(1-methylpropoxy)-
• CAS No.: 999-65-5
• Molecular Formula: C8H18O
• Molecular Weight: 130.23
• Hs Code.: 2909199090
• DSSTox Substance ID: DTXSID40337968
• Nikkaji Number: J121.179J
• Mol file: 999-65-5.mol

Synonyms:Butane, 1-(1-methylpropoxy)-;999-65-5;1-butan-2-yloxybutane;1-(SEC-BUTOXY)BUTANE;1-(1-Methylpropoxy)butane;1-s-butoxy-butane;Butyl 2-Butyl Ether;1-Sec-butoxybutane #;1-(1-methylpropoxy)-butane;SCHEMBL2759867;DTXSID40337968;AKOS030239628

Chemical Property of Butane, 1-(1-methylpropoxy)-

Chemical Property:

• Vapor Pressure: 10.8mmHg at 25°C
• Boiling Point: 132.6oC at 760 mmHg
• Flash Point: 22.8oC
• PSA: 9.23000
• Density: 0.778g/cm3
• LogP: 2.60160
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 130.135765193
• Heavy Atom Count: 9
• Complexity: 52.5

Purity/Quality:

95% ^*data from raw suppliers

Butyl2-ButylEther ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCOC(C)CC

Technology Process of Butane, 1-(1-methylpropoxy)-

There total 5 articles about Butane, 1-(1-methylpropoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.1%

butan-1-ol (71-36-3) → dibutyl ether (142-96-1) + 1-(1-methylpropoxy)butane (999-65-5)

Guidance literature:

With Amberlyst 36; at 150 ℃; for 7h; under 30.003 Torr; Catalytic behavior;

DOI:10.1016/j.apcata.2014.05.017

Reference yield: 16.6%

butan-1-ol (71-36-3) → trans-2-Butene (624-64-6) + dibutyl ether (142-96-1) + 1-(1-methylpropoxy)butane (999-65-5)

Guidance literature:

With Amberlyst 35; at 150 ℃; for 7h; under 30.003 Torr; Catalytic behavior;

DOI:10.1016/j.apcata.2014.05.017

Reference yield:

butan-1-ol (71-36-3) → 1-butylene (106-98-9,9003-28-5) + (Z)-2-Butene (590-18-1) + trans-2-Butene (624-64-6) + dibutyl ether (142-96-1) + 1-(1-methylpropoxy)butane (999-65-5)

Guidance literature:

With H-ZSM-5 zeolite; at 150 ℃; Product distribution; Kinetics; Mechanism; other dehydrated reagent, var. catalyst, var. temp., var. time;

DOI:10.1006/jcat.1994.1270

upstream raw materials:

butan-1-ol

methanol

Downstream raw materials:

(n-butyloxy)chloro-phenylborane

s-butyl chloride

butoxy-dichloro-borane

Refernces

• 1、 Gray, William K.,Smail, Fiona R.,Hitzler, Martin G.,Ross, Stephen K.,Poliakoff, Martyn. "The continuous acid-catalyzed dehydration of alcohols in supercritical fluids: A new approach to the cleaner synthesis of acetals, ketals, and ethers with high selectivity". . p. 10711 - 10718. Retrieved 2007/10/03.
• 2、 Ballantine, James A.,Davies, Mary,Purnell, Howard,Rayanakorn, Mongkon,Thomas, John M.,Williams, Kevin J.. "Chemical Conversions using Sheet Silicates: Novel Intermolecular Dehydrations of Alcohols to Ethers and Polymers". . p. 427 - 428. Retrieved 2007/10/02.