2-Decylpyridine

Base Information

• Chemical Name: 2-Decylpyridine
• CAS No.: 74421-02-6
• Molecular Formula: C15H25N
• Molecular Weight: 219.3657
• Hs Code.: 2933399090
• Mol file: 74421-02-6.mol

Synonyms:2-Decylpyridine;

Chemical Property of 2-Decylpyridine

Chemical Property:

• Boiling Point: 289.9 °C at 760 mmHg
• Flash Point: 147.3 °C
• PSA: 12.89000
• Density: 0.886 g/cm³
• LogP: 4.76480
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

2-Decylpyridine 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Decylpyridine

There total 7 articles about 2-Decylpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Iododecane (2050-77-3) + pyridin-2-ylzinc(II) bromide → 2-decylpyridine (74421-02-6)

Guidance literature:

pyridin-2-ylzinc(II) bromide; With (trimethylsilyl)methylmagnesium chloride; In tetrahydrofuran; diethyl ether; at 0 ℃; for 1h;

Iododecane; With N,N,N,N,-tetramethylethylenediamine; iron(III) chloride; In tetrahydrofuran; at 30 ℃; for 6h;

DOI:10.1055/s-2005-871541

Reference yield: 89.0%

undecanenitrile (2244-07-7) + acetylene (74-86-2,25067-58-7) → 2-decylpyridine (74421-02-6)

Guidance literature:

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I); In toluene; at 25 ℃; Irradiation;

DOI:10.1021/jo011032n

Reference yield: 78.0%

2-chloropyridine (109-09-1) + 1-bromo dodecane (112-29-8) → 2-decylpyridine (74421-02-6)

Guidance literature:

1-bromo dodecane; With iodine; magnesium; In diethyl ether; for 1h; Reflux;

2-chloropyridine; With iron(III) acetylacetonate; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.25h;

DOI:10.1002/ejoc.200701200

upstream raw materials:

α-picoline

pyridinium p-toluenesulfonate

undecanenitrile

acetylene

Refernces

• 1、 Midya, Siba P.,Landge, Vinod G.,Sahoo, Manoj K.,Rana, Jagannath,Balaraman, Ekambaram. "Cobalt-catalyzed acceptorless dehydrogenative coupling of aminoalcohols with alcohols: Direct access to pyrrole, pyridine and pyrazine derivatives". supporting information. p. 90 - 93. Retrieved 2017/12/27.
• 2、 -. "PROCESS FOR PRODUCTION OF AROMATIC COMPOUNDS". Page/Page column 30-32. . Retrieved 2010/11/24.