Imino(triphenyl)-lambda5-phosphane;hydrochloride

Base Information

• Chemical Name: Imino(triphenyl)-lambda5-phosphane;hydrochloride
• CAS No.: 21612-82-8
• Molecular Formula: C18H16NP
• Molecular Weight: 313.766
• NSC Number: 61677
• Mol file: 21612-82-8.mol

Synonyms:21612-82-8;Imino(triphenyl)-lambda5-phosphane;hydrochloride;triphenylphosphinimin-hydrochlorid;NSC61677;NSC-61677

Chemical Property of Imino(triphenyl)-lambda5-phosphane;hydrochloride

Chemical Property:

• Boiling Point: 404.7°Cat760mmHg
• Flash Point: 198.6°C
• Density: 1.09g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 313.0787142
• Heavy Atom Count: 21
• Complexity: 281

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=N)(C2=CC=CC=C2)C3=CC=CC=C3.Cl

Technology Process of Imino(triphenyl)-lambda5-phosphane;hydrochloride

There total 4 articles about Imino(triphenyl)-lambda5-phosphane;hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

<(diphenylmethylene)amino>triphenylphosphonium chloride (124842-07-5) + aniline (62-53-3) → N-(diphenylmethylidene)phenylamine (574-45-8) + P,P,P-triphenylphosphine imide hydrochloride (21612-82-8)

Guidance literature:

In acetonitrile; for 3h; Heating;

Reference yield: 91.0%

triphenylphosphine (603-35-0) → P,P,P-triphenylphosphine imide hydrochloride (21612-82-8) + triphenylphosphine sulfide (3878-45-3)

Guidance literature:

With S₄N₃Cl; In acetonitrile; at 30 ℃; for 24h; Product distribution; Mechanism; other cyclic sulphur-nitrogen chlorides; also in the presence of Et₃N, pyridine or Na₂CO₃; var. solvents;

Reference yield: 75.0%

(triphenylphosphoranediyl)aminocyclotrithiatriazene (33082-06-3) → P,P,P-triphenylphosphine imide hydrochloride (21612-82-8)

Guidance literature:

With diphenylsilyl dichloride; In acetonitrile; at 20 ℃;

DOI:10.1080/15533174.2010.538025

upstream raw materials:

triphenylphosphine

<(diphenylmethylene)amino>triphenylphosphonium chloride

aniline

(triphenylphosphoranediyl)aminocyclotrithiatriazene

Downstream raw materials:

[PhBP₃^iPr]Fe(NPPh₃)

N-(o-nitrophenylthio)-P,P,P-triphenylphosphine imide

Refernces

• 1、 Gopalakrishnan, Janarthanan,Swarnalatha, Ulaganathan,Rao, Sudheendra M. N.. "Halogenation reactions of phosphiniminocyclotrithiazenes: Search for new inorganic heterocycles". . p. 1324 - 1331. Retrieved 2016/04/26.
• 2、 Zhmurova, I. N.,Yurchenko, V. G.. "UNUSUAL CASE OF THE APPEL REACTION". . p. 42 - 45. Retrieved 2007/10/02.