3-Bromodibenzo[b,d]furan

Base Information

• Chemical Name: 3-Bromodibenzo[b,d]furan
• CAS No.: 26608-06-0
• Molecular Formula: C12H7 Br O
• Molecular Weight: 247.091
• Hs Code.: 2932999099
• NSC Number: 167387
• DSSTox Substance ID: DTXSID30304801
• Nikkaji Number: J139.669B
• Wikidata: Q82051017
• Mol file: 26608-06-0.mol

Synonyms:3-bromodibenzo[b,d]furan;26608-06-0;3-bromodibenzofuran;Dibenzofuran, 3-bromo-;3-bromo-dibenzofuran;MFCD09966042;3-Bromodibenzo[b,d]furan;3-bromo-Dibenzofuran,;NSC167387;SCHEMBL259160;AMY8885;DTXSID30304801;BCP15893;CS-D0380;AKOS016012317;DS-6885;NSC-167387;OL10189;SB66940;SY069415;B5451;FT-0696916;A854373

Chemical Property of 3-Bromodibenzo[b,d]furan

Chemical Property:

• Vapor Pressure: 0.000136mmHg at 25°C
• Melting Point: 232-233℃
• Refractive Index: 1.5290 (estimate)
• Boiling Point: 343.8°Cat760mmHg
• Flash Point: 161.7°C
• PSA: 13.14000
• Density: 1.577g/cm³
• LogP: 4.34850
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 245.96803
• Heavy Atom Count: 14
• Complexity: 218

Purity/Quality:

3-Bromodibenzo[b,d]furan ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=C(O2)C=C(C=C3)Br
• Uses: 3-Bromodibenzo[b,d]furan is a useful research chemical.

Technology Process of 3-Bromodibenzo[b,d]furan

There total 23 articles about 3-Bromodibenzo[b,d]furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

C12H8BrN2O(1+)*BF4(1-) → 3-bromodibenzofuran (26608-06-0)

Guidance literature:

With iron(II) sulfate; In water; at 80 ℃; for 5h; Large scale;

Reference yield: 80.0%

4-bromo-2-fluoro-2'-hydroxybiphenyl (1285719-49-4) → 3-bromodibenzofuran (26608-06-0)

Guidance literature:

With potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 185 ℃; for 1.5h;

Reference yield: 80.0%

2-phenoxy-4-bromobenzoic acid (861605-94-9) → 3-bromodibenzofuran (26608-06-0)

Guidance literature:

With acethylacetonato(1,5-cyclooctadiene)rhodium(I); potassium iodide; In acetic anhydride; at 160 ℃; for 10h; Inert atmosphere;

DOI:10.1021/ol4010905

upstream raw materials:

3-aminodibenzofuran

2-amino-5-bromodiphenyl ether

tert.-butylnitrite

copper(II)bromide

Downstream raw materials:

dibenzo[b,d]furan-3-carboxylic acid

dibenzofuran-4-carboxylic acid

3-hydroxydibenzofuran

3,7-dibromodibenzo[b,d]furan

Refernces

• 1、 -. "COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE". Paragraph 0305; 0308. . Retrieved 2020/02/10.
• 2、 -. "A 3 - benzofuran bromine two synthetic method (by machine translation)". Paragraph 0049; 0058; 0059. . Retrieved 2019/07/10.