Hexylsilane

Base Information

• Chemical Name: Hexylsilane
• CAS No.: 1072-14-6
• Deprecated CAS: 149158-62-3
• Molecular Formula: C6H16Si
• Molecular Weight: 116.279
• Hs Code.: 2931900090
• European Community (EC) Number: 214-001-0
• NSC Number: 168691
• UNII: CJ33K9XVJ5
• DSSTox Substance ID: DTXSID90883642
• Mol file: 1072-14-6.mol

Synonyms:Hexylsilane;n-Hexylsilane;1072-14-6;Silane, hexyl-;hexylsilicon;CJ33K9XVJ5;Silane,hexyl-;EINECS 214-001-0;NSC 168691;NSC-168691;NSC168691;C(CCC)CC[Si];UNII-CJ33K9XVJ5;Hexylsilane, >=97.0%;DTXSID90883642;QGGUMTNPIYCTSF-UHFFFAOYSA-N;MFCD00027291;A801879

Chemical Property of Hexylsilane

Chemical Property:

• Vapor Pressure: 29.9mmHg at 25°C
• Refractive Index: n20/D 1.414
• Boiling Point: 108.8 °C at 760 mmHg
• Flash Point: 19.6 °C
• PSA: 0.00000
• Density: 0.721 g/mL at 20 °C(lit.)
• LogP: 1.35040
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 113.078651949
• Heavy Atom Count: 7
• Complexity: 27.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

n-Hexylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F
• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCC[Si]

Technology Process of Hexylsilane

There total 8 articles about Hexylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

hexyltrichlorosilane (928-65-4) → hexylsilane (1072-14-6)

Guidance literature:

With lithium aluminium tetrahydride; In various solvent(s); for 4.5h;

DOI:10.1021/ja057947r

Reference yield: 67.0%

n-hexyltrimethoxysilane (3069-19-0) → hexylsilane (1072-14-6)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide; In benzene-d6; at 20 ℃; for 24h;

DOI:10.1039/c9cc01961h

Reference yield: 37.4%

1-hexene (592-41-6,25067-06-5) → hexylsilane (1072-14-6) + (1-hexyl)(hexyl)silane (1002-78-4)

Guidance literature:

With lithium aluminium tetrahydride; monosilane; at 160 ℃; for 20h; under 22065.2 - 29420.3 Torr;

DOI:10.1246/cl.1996.1013

upstream raw materials:

hexyltrichlorosilane

hexyltriethoxysilane

1-hexene

n-hexylmagnesium bromide

Downstream raw materials:

N,N-diethylhexylamine

C₁₄H₂₄Si

(1-hexyl)(hexyl)silane

(E)-1-phenyl-2-phenyl-2-(hexylsilyl)ethene

Refernces

• 1、 Aoyagi, Keiya,Ohmori, Yu,Inomata, Koya,Matsumoto, Kazuhiro,Shimada, Shigeru,Sato, Kazuhiko,Nakajima, Yumiko. "Synthesis of hydrosilanes: Via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4". . p. 5859 - 5862. Retrieved 2019.
• 2、 -. "PROCESS FOR THE STEPWISE SYNTHESIS OF SILAHYDROCARBONS". Page/Page column 73. . Retrieved 2021/12/08.
• 3、 -. "MANUFACTURING METHOD OF HYDROSILANE". Paragraph 0037-0038. . Retrieved 2019/07/13.