1,1-DICHLORONONANE

Base Information

• Chemical Name: 1,1-DICHLORONONANE
• CAS No.: 821-88-5
• Molecular Formula: C₉H₁₈Cl₂
• Molecular Weight: 197.148
• Mol file: 821-88-5.mol

Synonyms:

Chemical Property of 1,1-DICHLORONONANE

Chemical Property:

• Vapor Pressure: 0.0833mmHg at 25°C
• Boiling Point: 233.9°Cat760mmHg
• Flash Point: 91.1°C
• Density: 0.984g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1-DICHLORONONANE

There total 12 articles about 1,1-DICHLORONONANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

chloroform (67-66-3,8013-54-5) + oct-1-ene (111-66-0,25068-25-1) → 1,1-dichlorononane (821-88-5)

Guidance literature:

With sodium dithionite; sodium hydrogencarbonate; In dimethyl sulfoxide; at 80 ℃; for 5h;

DOI:10.1021/jo9900937

Reference yield: 73.0%

2-(1-chlorononyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane → 1,1-dichlorononane (821-88-5)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 2-methoxybenzo[d][1,3,2]dioxaborole; benzenesulfonyl chloride; In methanol; dichloromethane; benzene; at 70 ℃; for 16h; Inert atmosphere;

DOI:10.1002/anie.202004012

Reference yield: 70.0%

nonan-1-al (124-19-6) → 1,1-dichlorononane (821-88-5)

Guidance literature:

With tetrachloromethane; triphenylphosphine; In tetrahydrofuran; 1) 25 deg C, 3h, 2) RT, overnight;

DOI:10.1016/S0040-4039(00)92342-6

upstream raw materials:

nonan-1-al

chloroform

oct-1-ene

1,1,1-trichlorononane

Refernces

• 1、 André-Joyaux, Emy,Kuzovlev, Andrey,Renaud, Philippe,Tappin, Nicholas D. C.. "A General Approach to Deboronative Radical Chain Reactions with Pinacol Alkylboronic Esters". supporting information. p. 13859 - 13864. Retrieved 2020/06/10.
• 2、 Kiseleva, L. N.,Rybakova, N. A.,Kuz'mina, N. A.,Vasil'eva T. T.,Dostovalova, V. I.. "HYDROGEN MIGRATION ON 1,1-DICHLOROALKYL RADICALS". . p. 1719 - 1722. Retrieved 2007/10/02.