1-Bromo-4-(pentyloxy)benzene

Base Information

• Chemical Name: 1-Bromo-4-(pentyloxy)benzene
• CAS No.: 30752-18-2
• Molecular Formula: C11H15BrO
• Molecular Weight: 243.143
• Hs Code.: 29051900
• DSSTox Substance ID: DTXSID40426881
• Nikkaji Number: J156.344K
• Wikidata: Q82239673
• Mol file: 30752-18-2.mol

Synonyms:30752-18-2;1-Bromo-4-pentoxy-benzene;1-bromo-4-(pentyloxy)benzene;4-(n-pentyloxy)bromobenzene;4-n-Amyloxybromobenzene;1-bromo-4-pentyloxybenzene;1-bromo-4-pentoxybenzene;1-Bromo-4-(n-pentyloxy)benzene;4-n-Pentyloxybromobenzene;4-Bromophenylpentyl ether;SCHEMBL917938;4-Bromophenol, n-pentyl ether;8-BROMO-2-DEOXYADENOSINE;DTXSID40426881;MFCD00156123;AKOS009156413;CS-0195390;FT-0638937;F13654;A820607;J-513798

Chemical Property of 1-Bromo-4-(pentyloxy)benzene

Chemical Property:

• Vapor Pressure: 0.00609mmHg at 25°C
• Refractive Index: 1.516
• Boiling Point: 281.4 °C at 760 mmHg
• Flash Point: 120.5 °C
• PSA: 9.23000
• Density: 1.242 g/cm³
• LogP: 4.01810
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 242.03063
• Heavy Atom Count: 13
• Complexity: 119

Purity/Quality:

99% ^*data from raw suppliers

4-N-Amyloxybromobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCOC1=CC=C(C=C1)Br
• Uses: 4-N-AMYLOXYBROMOBENZENE is a useful research chemical.

Technology Process of 1-Bromo-4-(pentyloxy)benzene

There total 19 articles about 1-Bromo-4-(pentyloxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pentan-1-ol (71-41-0) + 1,2-dichloro-benzene (95-50-1) → 1-bromo-4-pentyloxybenzene (30752-18-2) + 2-chlorophenyl pentyl ether (51241-39-5) + chlorobenzene (108-90-7)

Guidance literature:

With potassium hydroxide; PEG-6000; at 150 ℃; for 6h; Yields of byproduct given;

DOI:10.1016/S0040-4020(01)91597-2

Reference yield: 97.6%

→ 1-bromo-4-pentyloxybenzene (30752-18-2)

Guidance literature:

With potassium carbonate; In acetone; for 0.166667h; Sealed tube; Inert atmosphere;

In acetone; for 24h; Reflux;

Reference yield: 97.0%

(pentyloxy)benzene (2050-04-6) → 1-bromo-4-pentyloxybenzene (30752-18-2)

Guidance literature:

With kaolin; sodium chlorite; manganese(III) acetylacetonate; sodium bromide; In dichloromethane; at 25 ℃; for 2.16667h;

DOI:10.1039/a804043e

upstream raw materials:

4-bromo-phenol

1-Bromopentane

bromochlorobenzene

pentan-1-ol

Downstream raw materials:

2-[4-(pentyloxy)phenyl]-4-(2,6,6-trimethylcyclohex-1-enyl)but-3-en-2-ol

4′′-(pentyloxy)-1,1′:4′,1′′-terphenyl-4-carboxylic acid

2-chloro-5-(4-pentyloxy-benzoyl)-benzenesulfonamide

1-(4-n-pentyloxyphenyl)-2-trimethylsilylacetylene

Refernces

• 1、 Wang, Ze-Zhong,Wang, Guang-Zu,Zhao, Bin,Shang, Rui,Fu, Yao. "Cobalt-Catalyzed Decarboxylative Methylation and Ethylation of Aliphatic N-(Acyloxy)phthalimides with Organoaluminum Reagents". supporting information. p. 1221 - 1225. Retrieved 2020/08/17.
• 2、 W?hrle, Tobias,Gündemir, Rafet,Frey, Wolfgang,Knecht, Friederike,K?hn, Andreas,Laschat, Sabine. "Thermotropic MIDA Boronates as a Case Study for the Role of Dipolar Interactions in Liquid Crystalline Self-Assembly". supporting information. p. 4149 - 4159. Retrieved 2017/03/31.