Phenyl-t-butylether

Base Information

• Chemical Name: Phenyl-t-butylether
• CAS No.: 6669-13-2
• Molecular Formula: C10H14 O
• Molecular Weight: 150.221
• Hs Code.: 2909309090
• Mol file: 6669-13-2.mol

Synonyms:Ether,tert-butyl phenyl (6CI,7CI,8CI); 1,1-Dimethylethyl phenyl ether; NSC 78717;Phenyl tert-butyl ether; tert-Butoxybenzene; tert-Butyl phenyl ether

Chemical Property of Phenyl-t-butylether

Chemical Property:

• Vapor Pressure: 0.953mmHg at 25°C
• Melting Point: -17--16℃
• Refractive Index: 1.488
• Boiling Point: 184°C
• Flash Point: 184°C
• PSA: 9.23000
• Density: 0.924
• LogP: 2.86390
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99%, ^*data from raw suppliers

tert-Butoxybenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: tert-Butoxybenzene was studied in the analysis of the color and flavor improvement of different starter cultures on northern air-dried sausage.

Technology Process of Phenyl-t-butylether

There total 50 articles about Phenyl-t-butylether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

bromobenzene (108-86-1,52753-63-6) + N,N'-dibenzylpiperazine-2,5-dione (42492-87-5) → biphenyl (92-52-4,1594-86-1) + t-butyl phenyl ether (6669-13-2)

Guidance literature:

With potassium tert-butylate; In benzene; at 130 ℃; for 18h; Inert atmosphere;

DOI:10.1039/c7ob00036g

Reference yield: 50.41%

1-butylene (106-98-9,9003-28-5) + isobutene (115-11-7,15220-85-6) + phenol (108-95-2,27073-41-2) → 2-sec-butylphenol (89-72-5) + t-butyl phenyl ether (6669-13-2) + 2-sec-butyl-4-tert-butylphenol

Guidance literature:

aluminum oxide; at 220 ℃; for 6h; Autoclave;

Reference yield: 49.0%

1-butylene (106-98-9,9003-28-5) + isobutene (115-11-7,15220-85-6) + phenol (108-95-2,27073-41-2) → 2-sec-butylphenol (89-72-5) + t-butyl phenyl ether (6669-13-2)

Guidance literature:

aluminum oxide; at 150 ℃; for 7h; Autoclave;

upstream raw materials:

tert-Butyl peroxybenzoate

t-butyl bromide

sodium phenoxide

isobutene

Downstream raw materials:

C₂₀H₂₇O₃P

para-tert-butylphenol

2-tert-Butylphenol

phenol

Refernces

• 1、 Brevet,Lucas,Cattey,Lemaitre,Mugnier,Harvey. "Electrochemically induced C-Br and C-I bond activation by the Pd3(dppm)3Co2+ cluster, and characterization of the reactive Pd3(dppm)3Co+ intermediate: The first confidently identified param". . p. 4340 - 4341. Retrieved 2001.
• 2、 Sharif, Sepideh,Rodriguez, Michael J.,Lu, Yu,Kopach, Michael E.,Mitchell, David,Hunter, Howard N.,Organ, Michael G.. "Sodium Butylated Hydroxytoluene (NaBHT) as a New and Efficient Hydride Source for Pd-Catalysed Reduction Reactions". supporting information. p. 13099 - 13103. Retrieved 2019/10/28.
• 3、 Pedroli, Chiara,Ravelli, Davide,Protti, Stefano,Albini, Angelo,Fagnoni, Maurizio. "Singlet vs Triplet Reactivity of Photogenerated α,n-Didehydrotoluenes". supporting information. p. 6592 - 6603. Retrieved 2017/07/15.