oxiranylmethyl acetoacetate

Base Information

• Chemical Name: oxiranylmethyl acetoacetate
• CAS No.: 84643-60-7
• Molecular Formula: C7H10 O4
• Molecular Weight: 158.154
• Hs Code.: 2918300090
• Mol file: 84643-60-7.mol

Synonyms:Butanoicacid, 3-oxo-, oxiranylmethyl ester (9CI); Glycidyl acetoacetate

Chemical Property of oxiranylmethyl acetoacetate

Chemical Property:

• Vapor Pressure: 0.0395mmHg at 25°C
• Boiling Point: 239.7°C at 760 mmHg
• Flash Point: 100.7°C
• PSA: 55.90000
• Density: 1.198g/cm³
• LogP: -0.09250

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxiranylmethyl acetoacetate

There total 4 articles about oxiranylmethyl acetoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

oxiranyl-methanol (556-52-5) + acetoacetic acid methyl ester (105-45-3) → oxiran-2-ylmethyl 3-oxobutanoate (84643-60-7)

Guidance literature:

niobium(V) oxide; In toluene; for 5.5h; Heating;

DOI:10.1016/j.tetlet.2005.01.158

Reference yield: 73.0%

tert-butyl acetoacetate (1694-31-1) + oxiranyl-methanol (556-52-5) → oxiran-2-ylmethyl 3-oxobutanoate (84643-60-7)

Guidance literature:

In toluene; for 2h; Heating;

DOI:10.1021/jo00005a013

Reference yield: 58.0%

oxiranyl-methanol (556-52-5) + ethyl acetoacetate (141-97-9) → oxiran-2-ylmethyl 3-oxobutanoate (84643-60-7)

Guidance literature:

niobium(V) oxide; In toluene; for 5h; Heating;

DOI:10.1016/j.tetlet.2005.01.158

upstream raw materials:

tert-butyl acetoacetate

oxiranyl-methanol

ethyl acetoacetate

acetoacetic acid methyl ester

Refernces

• 1、 De Sairre, Mirela Inês,Bronze-Uhle, érika Soares,Donate, Paulo Marcos. "Niobium(V) oxide: A new and efficient catalyst for the transesterification of β-keto esters". . p. 2705 - 2708. Retrieved 2007/10/03.