C7-H7-Br-Mg

Base Information

• Chemical Name: C7-H7-Br-Mg
• CAS No.: 1589-82-8
• Molecular Formula: C7H7BrMg
• Molecular Weight: 195.342
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID80936015
• Mol file: 1589-82-8.mol

Synonyms:C7-H7-Br-Mg;DTXSID80936015;BAA58982;Magnesium bromide 6-methylidenecyclohexa-2,4-dien-1-ide (1/1/1)

Chemical Property of C7-H7-Br-Mg

Chemical Property:

• Appearance/Colour: powder
• Vapor Pressure: 27.7mmHg at 25°C
• Boiling Point: 110.6°C at 760 mmHg
• Flash Point: 10°C
• PSA: 0.00000
• LogP: 2.84790
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 193.95815
• Heavy Atom Count: 9
• Complexity: 42

Purity/Quality:

99% ^*data from raw suppliers

MagnesiumMethanidylbenzeneBromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2-]C1=CC=CC=C1.[Mg+2].[Br-]

Technology Process of C7-H7-Br-Mg

There total 6 articles about C7-H7-Br-Mg which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl bromide (100-39-0) → phenylmagnesium bromide (1589-82-8) + 1,1'-(1,2-ethanediyl)bisbenzene (103-29-7)

Guidance literature:

With diethyl ether; magnesium;

Reference yield:

benzyl bromide (100-39-0) → phenylmagnesium bromide (1589-82-8)

Guidance literature:

With magnesium; In diethyl ether; Thermodynamic data; -ΔH(reaction);

Reference yield:

benzyl bromide (100-39-0) + 2-Bromo-3-(methoxymethoxy)pyridine (162271-10-5) → phenylmagnesium bromide (1589-82-8)

Guidance literature:

With ammonium chloride; magnesium; In tetrahydrofuran; diethyl ether;

upstream raw materials:

benzyl bromide

benzyl chloride

magnesium

2-Bromo-3-(methoxymethoxy)pyridine

Downstream raw materials:

2-benzylquinoline

1-(furan-2-yl)-2-phenylethanol

(E)-2-(2-phenylethenyl)thiophene

benzyl 2-pyridyl ketone

Refernces

• 1、 Mills, L. Reginald,Rousseaux, Sophie A.L.. "A one-pot electrophilic cyanation–functionalization strategy for the synthesis of disubstituted malononitriles". . p. 4298 - 4306. Retrieved 2019/05/22.
• 2、 Boukattaya, Fatma,Caillé, Julien,Ammar, Houcine,Rouzier, Florian,Boeda, Fabien,Pearson-Long, Morwenna S. M.,Bertus, Philippe. "A Short Access to Symmetrically α,α-Disubstituted α-Amino Acids from Acyl Cyanohydrins". . p. 906 - 916. Retrieved 2016/03/12.