trans-2-Nonene

Base Information

• Chemical Name: trans-2-Nonene
• CAS No.: 6434-78-2
• Molecular Formula: C9H18
• Molecular Weight: 126.242
• European Community (EC) Number: 229-216-5,678-276-2
• UNII: W20AXW806F
• DSSTox Substance ID: DTXSID60883134
• Nikkaji Number: J87.937A,J87.938J
• Wikidata: Q27292204
• Mol file: 6434-78-2.mol

Synonyms:trans-2-Nonene;6434-78-2;2-Nonene;(E)-Non-2-ene;2-Nonene, (E)-;(E)-2-Nonene;2-Nonene, (2E)-;(2E)-2-Nonene;UNII-W20AXW806F;(2E)-NON-2-ENE;HSDB 756;W20AXW806F;EINECS 229-216-5;EINECS 248-339-5;2216-38-8;Noneno;n-Nonenes;n-Nonene;MFCD00009549;UNII-M0TB9RXK4B;Nonene (all isomers);EC 248-339-5;.BETA.-TRANS-NONENE;DTXSID60883134;CAA21638;(E)-2-C9H18;LS-166168;D91716;ethyl[2-(boc-amino)ethylamino]acetatehydrochloride;Q27292204

Chemical Property of trans-2-Nonene

Chemical Property:

• Melting Point: -89.14°C (estimate)
• Refractive Index: n20/D 1.42(lit.)
• Boiling Point: 150.5°Cat760mmHg
• Flash Point: 32.2°C
• PSA: 0.00000
• Density: 0.739g/cm³
• LogP: 3.53290
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 126.140850574
• Heavy Atom Count: 9
• Complexity: 62.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16-29-33

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCC=CC
• Isomeric SMILES: CCCCCC/C=C/C

Technology Process of trans-2-Nonene

There total 72 articles about trans-2-Nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(RR,SS)-3-dimethyl(phenyl)silylnonan-2-ol → 2-nonene (6434-78-2)

Guidance literature:

With potassium hydride; In tetrahydrofuran; for 0.5h; Ambient temperature;

DOI:10.1016/0022-328X(84)85181-5

Reference yield: 79.0%

1-bromo-1-cyclopropylethane (80204-20-2) → 2-nonene (6434-78-2)

Guidance literature:

In diethyl ether; at -24 ℃; for 4.5h;

DOI:10.1016/S0040-4020(01)91792-2

Reference yield: 65.0%

2-nonenyl alcohol (31502-14-4) → nonane (111-84-2) + non-1-ene (124-11-8) + 2-nonene (6434-78-2) + nonyl alcohol (143-08-8)

Guidance literature:

With methanol; toluene-4-sulfonic acid; at 25 ℃; for 5h; Reagent/catalyst; Inert atmosphere; Sealed tube; UV-irradiation;

upstream raw materials:

nonan-3-ol

nonan-2-ol

oct-1-ene

non-2-yne

Downstream raw materials:

3-nonanone

2-Nonanone

oenanthic acid

nonane

Refernces

• 1、 Lamb, Jessica R.,Hubbell, Aran K.,MacMillan, Samantha N.,Coates, Geoffrey W.. "Carbonylative, Catalytic Deoxygenation of 2,3-Disubstituted Epoxides with Inversion of Stereochemistry: An Alternative Alkene Isomerization Method". supporting information. p. 8029 - 8035. Retrieved 2020/05/01.
• 2、 Takada, Yuki,Caner, Joaquim,Kaliyamoorthy, Selvam,Naka, Hiroshi,Saito, Susumu. "Photocatalytic Transfer Hydrogenolysis of Allylic Alcohols on Pd/TiO2: A Shortcut to (S)-(+)-Lavandulol". supporting information. p. 18025 - 18032. Retrieved 2017/12/08.