Hexafluoroisopropyl methacrylate

Base Information

• Chemical Name: Hexafluoroisopropyl methacrylate
• CAS No.: 3063-94-3
• Deprecated CAS: 1443044-90-3
• Molecular Formula: C₇H₆F₆O₂
• Molecular Weight: 236.114
• Hs Code.: 29161900
• European Community (EC) Number: 221-309-9
• UNII: DPH4JT6JRF
• DSSTox Substance ID: DTXSID50883729
• Nikkaji Number: J205.370E
• Wikidata: Q72481729
• Mol file: 3063-94-3.mol

Synonyms:3063-94-3;Hexafluoroisopropyl methacrylate;1,1,1,3,3,3-Hexafluoroisopropyl methacrylate;HFIPMA;1,1,1,3,3,3-hexafluoropropan-2-yl 2-methylprop-2-enoate;2-Propenoic acid, 2-methyl-, 2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester;1,1,1,3,3,3-HEXAFLUOROISOPROPYLMETHACRYLATE;2,2,2-Trifluoro-1-(trifluoromethyl)ethyl methacrylate;C7H6F6O2;DPH4JT6JRF;EINECS 221-309-9;1,1,1,3,3,3-HEXAFLUORO-2-PROPYL METHACRYLATE;Methacrylic Acid 1,1,1,3,3,3-Hexafluoroisopropyl Ester;1,1,1,3,3,3-Hexafluoroisopropyl methacrylate (stabilized with MEHQ);HFIP-M;VISCOAT 6FM;UNII-DPH4JT6JRF;1,1,1,3,3,3-Hexafluoroisoropropyl methacrylate;SCHEMBL47311;FMQPBWHSNCRVQJ-UHFFFAOYSA-;1,1,1,3,3,3-HEXAFLUOROPROPAN-2-YL METHACRYLATE;AMY6850;DTXSID50883729;diperfluoromethylmethyl methacrylate;C7-H6-F6-O2;MFCD00040105;AKOS005257996;HEXAFLUORO-2-PROPYL METHACRYLATE;MS-20605;CS-0127663;FT-0605918;M0988;1,1,1,3,3,3-Hexafluoroisopropyl methacrylate, 99%;1H-1-(TRIFLUOROMETHYL)TRIFLUOROETHYL METHACRYLATE;6-PHENYLNICOTINONITRILE97+%3-CYANO-6-PHENYLPIRIDINE;2,2,2-Trifluoro-1-(trifluoromethyl)ethyl 2-methylacrylate #;1,1,1,3,3,3-Hexafluoroisopropyl methacrylate(stabilizedwithMEHQ);1,1,1,3,3,3-Hexafluoroisopropyl Methacrylate, (stabilized with MEHQ);METHACRYLIC ACID, 2,2,2-TRIFLUORO-1-(TRIFLUOROMETHYL)ETHYL ESTER

Chemical Property of Hexafluoroisopropyl methacrylate

Chemical Property:

• Appearance/Colour: Clear colorless liquid
• Vapor Pressure: 0.71 psi ( 20 °C)
• Refractive Index: n20/D 1.331(lit.)
• Boiling Point: 149.145 °C at 760 mmHg
• Flash Point: 33.885 °C
• PSA: 26.30000
• Density: 1.302 g/mL at 25ºC(lit.)
• LogP: 2.59890
• Storage Temp.: Flammables area
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 3
• Exact Mass: 236.02719840
• Heavy Atom Count: 15
• Complexity: 250

Purity/Quality:

99% ^*data from raw suppliers

1,1,1,3,3,3-Hexafluoroisopropyl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xn,Xi
• Hazard Codes: F,Xn,Xi
• Statements: 11-20/21/22-36/37/38
• Safety Statements: 16-26-33-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC(C(F)(F)F)C(F)(F)F

Technology Process of Hexafluoroisopropyl methacrylate

There total 2 articles about Hexafluoroisopropyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1,3',3',3'-hexafluoro-propanol (920-66-1) + Methacryloyl chloride (920-46-7,26937-45-1) → 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate (3063-94-3)

Guidance literature:

With triethylamine; hydroquinone; In cyclohexanone; at 5 - 40 ℃; for 3h;

Reference yield:

methacryloyl anhydride (760-93-0) + 1,1,1,3',3',3'-hexafluoro-propanol (920-66-1) → 1,1,1,3,3,3-Hexafluoroisopropyl methacrylate (3063-94-3)

Guidance literature:

With tempol; 2,4-dimethyl-6-tert-butylphenol; 4-methoxy-phenol; magnesium bromide; at 90 ℃; for 6h; Reagent/catalyst;

upstream raw materials:

methacryloyl anhydride

1,1,1,3',3',3'-hexafluoro-propanol

Methacryloyl chloride

Refernces

• 1、 -. "PREPARATION OF (METH)ACRYLIC ACID ESTERS". Page/Page column 15-16. . Retrieved 2020/03/05.