Dichloro(diisopropoxy)titanium

Base Information

• Chemical Name: Dichloro(diisopropoxy)titanium
• CAS No.: 762-99-2
• Deprecated CAS: 15972-80-2
• Molecular Formula: C6H14 Cl2 O2 Ti
• Molecular Weight: 236.962
• European Community (EC) Number: 212-106-6
• Mol file: 762-99-2.mol

Synonyms:Dichloro(diisopropoxy)titanium;762-99-2;Dichlorotitanium Diisopropoxide;dichlorotitanium;propan-2-ol;TiCl2(Oi-Pr)2;SCHEMBL477445;Dichlorobis(propan-2-olato)titanium;EINECS 212-106-6;MFCD00191416;CS-0086069

Chemical Property of Dichloro(diisopropoxy)titanium

Chemical Property:

• Melting Point: 42-43 °C
• PSA: 18.46000
• LogP: 3.13040
• Storage Temp.: Freezer
• Solubility.: soluble in Chloroform
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 238.000676
• Heavy Atom Count: 11
• Complexity: 47.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dichlorotitanium Diisopropoxide ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)O.CC(C)O.Cl[Ti]Cl

Technology Process of Dichloro(diisopropoxy)titanium

There total 4 articles about Dichloro(diisopropoxy)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

titanium(IV) isopropylate (546-68-9) + titanium tetrachloride (7550-45-0) → titanium(IV) dichlorodiisopropylate (762-99-2)

Guidance literature:

In tetrachloromethane; Ti-isopropoxide added slowly under N2 to a stirred soln. of TiCl4 at 0°C, allowed to warm to 20°C and stirred for 1h at this temp.; evapd. (atm. pressure), distn.;

Reference yield:

titanium(IV) isopropylate (546-68-9) → titanium(IV) dichlorodiisopropylate (762-99-2)

Guidance literature:

titanium tetrachloride; In hexane;

Reference yield:

iPr2Ti(OiPr)2 (488728-52-5) + titanium tetrachloride (7550-45-0) → titanium(IV) dichlorodiisopropylate (762-99-2)

Guidance literature:

In dichloromethane;

DOI:10.1016/j.tet.2012.10.022

upstream raw materials:

titanium(IV) isopropylate

titanium tetrachloride

iPr₂Ti(OiPr)2

Downstream raw materials:

isopropyl alcohol

(TosO)2Ti(O-iPr)2

dichloro[(M)-6,6'-dimethyl-α,α,α',α'-tetraphenyl[1,1'-biphenyl]-2,2'-dimethanolato(2-)-κO,κO']titanium

Refernces

• 1、 Mikami, Koichi,Motoyama, Yukihiro,Terada, Masahiro. "". . p. 71 - 76. Retrieved 1994.
• 2、 Nassar, Youssef,Piva, Olivier. "A short route to access oxaspiro[: N,3,3]propellanes". supporting information. p. 5811 - 5815. Retrieved 2020/08/21.
• 3、 -. "New synthetic method of antibacterial natural product Ieodomycin B". Paragraph 0038. . Retrieved 2017/10/26.