1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI)

Base Information

• Chemical Name: 1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI)
• CAS No.: 75435-17-5
• Molecular Formula: C7H4 O4
• Molecular Weight: 152.106
• Mol file: 75435-17-5.mol

Synonyms:1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI)

Chemical Property of 1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI)

Chemical Property:

• Vapor Pressure: 0.000647mmHg at 25°C
• Boiling Point: 287.1°C at 760 mmHg
• Flash Point: 141.7°C
• PSA: 71.44000
• Density: 1.579g/cm³
• LogP: -0.29460

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: 1,5-Cyclohexadiene-1-carboxylic acid, 3,4-dioxo-(7CI,9CI), a specific chemical compound, serves varied functions across diverse fields. In the pharmaceutical sector, it can serve as a potential intermediate in the synthesis of complex molecules with potential therapeutic applications, contributing to drug discovery and development efforts. In organic chemistry, this compound can act as a building block, enabling the creation of intricate molecular structures and supporting advancements in chemical research. Additionally, in the field of materials science, it might find use in developing specialized materials with unique properties. The compound's versatile applications in pharmaceuticals, chemistry, and materials science highlight its significance in driving innovation, scientific exploration, and practical solutions across these distinct domains.

Technology Process of 1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI)

There total 7 articles about 1,5-Cyclohexadiene-1-carboxylicacid,3,4-dioxo-(7CI,9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4-Dihydroxybenzoic acid (99-50-3) → 3,4-dioxocyclohexa-1,5-diene-1-carboxylic acid (75435-17-5)

Guidance literature:

With trans-cyclo-1,2-diamine-NNN'N'-tetra-acetatomanganate(III); at 10 ℃; Kinetics; pH=2.5, other pH values, other temperature;

DOI:10.1039/DT9830000689

Reference yield:

tert.-butylhydroperoxide (75-91-2) + 4-hydroxy-benzoic acid (99-96-7) → 3,4-dioxocyclohexa-1,5-diene-1-carboxylic acid (75435-17-5) + p-benzoquinone (106-51-4)

Guidance literature:

With dirhodium(II) tetrakis(caprolactam); In water; chlorobenzene; at 40 ℃; for 3h;

DOI:10.1021/jo1024865

Reference yield:

3,4-Dihydroxybenzoic acid (99-50-3) + d(4)-methanol (811-98-3) → 3-hydroxy-3-methoxy-4-oxocyclohexa-1,5-dienecarboxylic acid + 3,4-dioxocyclohexa-1,5-diene-1-carboxylic acid (75435-17-5)

Guidance literature:

With 2,2-diphenyl-1-picrylhydrazine; In acetone; Title compound not separated from byproducts;

DOI:10.1002/hlca.200690139

upstream raw materials:

3,4-Dihydroxybenzoic acid

methanol

d⁽⁴⁾-methanol

tert.-butylhydroperoxide

Refernces

• 1、 Arvinte, Adina,Carp, Oana Elena,Moraru, Aurelian,Pinteala, Mariana. "Electrochemical behaviour of piperine. Comparison with control antioxidants". . . Retrieved 2021.
• 2、 Sentandreu, Enrique,Navarro, Jose L.,Sendra, Jose M.. "Reduction kinetics of the antiradical probe 2,2-diphenyl-1-picrylhydrazyl in methanol and acetonitrile by the antiradical activity of protocatechuic acid and protocatechuic acid methyl ester". . p. 4928 - 4936. Retrieved 2008.
• 3、 Munoz-Munoz, Jose Luis,Garcia-Molina, Francisco,Berna, Jose,Garcia-Ruiz, Pedro Antonio,Varon, Ramon,Tudela, Jose,Rodriguez-Lopez, Jose N.,Garcia-Canovas, Francisco. "Kinetic characterisation of o-aminophenols and aromatic o-diamines as suicide substrates of tyrosinase". experimental part. p. 647 - 655. Retrieved 2012/08/08.