Dioxosuccinic acid

Base Information

• Chemical Name: Dioxosuccinic acid
• CAS No.: 7580-59-8
• Molecular Formula: C4H2 O6
• Molecular Weight: 146.056
• European Community (EC) Number: 231-483-8
• UNII: D82LW8DKT2
• DSSTox Substance ID: DTXSID30226716
• Nikkaji Number: J61.296K
• Wikipedia: Dioxosuccinic_acid
• Wikidata: Q5279654
• Metabolomics Workbench ID: 54250
• Mol file: 7580-59-8.mol

Synonyms:Dioxosuccinic acid;2,3-Dioxosuccinic acid;7580-59-8;2,3-dioxobutanedioic acid;diketosuccinic acid;D82LW8DKT2;EINECS 231-483-8;C4H2O6;2,3-Dioxosuccinicacid;UNII-D82LW8DKT2;DIOXOBUTANEDIOIC ACID;SCHEMBL6310940;CHEBI:30799;DTXSID30226716;C4-H2-O6;AKOS006380501;BUTANEDIOIC ACID, 2,3-DIOXO-;Q5279654

Chemical Property of Dioxosuccinic acid

Chemical Property:

• Vapor Pressure: 3.22E-09mmHg at 25°C
• Melting Point: 114 °C
• Boiling Point: 446.5°C at 760 mmHg
• PKA: 0.61±0.54(Predicted)
• Flash Point: 238°C
• PSA: 108.74000
• Density: 1.871g/cm³
• LogP: -1.70620
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 145.98513778
• Heavy Atom Count: 10
• Complexity: 190

Purity/Quality:

98% ^*data from raw suppliers

2,3-DIOXOSUCCINIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)(C(=O)C(=O)O)C(=O)O

Technology Process of Dioxosuccinic acid

There total 19 articles about Dioxosuccinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

meso-tartaric acid (138508-61-9) → dioxosuccinic acid (7580-59-8)

Guidance literature:

With N-Bromosuccinimide; In tetrachloromethane; for 1h; Heating;

DOI:10.1016/S0040-4039(03)01075-X

Reference yield: 82.0%

L-(+)-tartaric acid (87-69-4,133-37-9,147-71-7,147-73-9,526-83-0,138508-61-9) → dioxosuccinic acid (7580-59-8)

Guidance literature:

With N-Bromosuccinimide; In tetrachloromethane; for 1.5h; Heating;

DOI:10.1016/S0040-4039(03)01075-X

Reference yield:

dihydroxyfumaric acid (133-38-0) → dioxosuccinic acid (7580-59-8)

Guidance literature:

With selenium(IV) oxide; water;

upstream raw materials:

3,4-Dihydroxybenzoic acid

dihydroxyfumaric acid

dihydroxymaleic acid

benzene-1,2-diol

Downstream raw materials:

tartronic acid

2,4-imidazolidinedione

carbon dioxide

anilino-malonic acid

Refernces

• 1、 Barth. "-". . p. 869. Retrieved 1880.
• 2、 Hu, Sheng-Li,Wang, Shuai,Li, Yi-Tao,Cao, Li-Ping,Wu, An-Xin. "Synthesis and binding properties of two new fluorescent molecular clips based on diethoxycarbonyl glycoluril". scheme or table. p. 32 - 34. Retrieved 2009/10/02.
• 3、 Li, Yitao,Zhu, Yanping,Qin, Jing,Guo, Huizhen,Li, Lin,Wu, Anxin. "Synthesis of self-folded molecular rotors controlled by edge-to-face CH/π aromatic interactions". scheme or table. p. 2028 - 2034. Retrieved 2009/12/31.