NONAFLUORO-1-BUTANESULFONYL CHLORIDE

Base Information

• Chemical Name: NONAFLUORO-1-BUTANESULFONYL CHLORIDE
• CAS No.: 2991-84-6
• Molecular Formula: C4Cl F9 O2 S
• Molecular Weight: 318.547
• Hs Code.: 2904909090
• Mol file: 2991-84-6.mol

Synonyms:1-Butanesulfonylchloride, nonafluoro- (6CI); 1,1,2,2,3,3,4,4,4-Nonafluoro-1-butanesulfonylchloride; NSC 292150; Perfluorobutanesulfonyl chloride; Perfluorobutylsulfonylchloride

Chemical Property of NONAFLUORO-1-BUTANESULFONYL CHLORIDE

Chemical Property:

• Vapor Pressure: 28.9mmHg at 25°C
• Boiling Point: 109.6°Cat760mmHg
• Flash Point: 20.1°C
• PSA: 42.52000
• Density: 1.807g/cm³
• LogP: 4.06150
• Sensitive.: Moisture Sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

Nonafluorobutanesulfonyl chloride 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C,Xi
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of NONAFLUORO-1-BUTANESULFONYL CHLORIDE

There total 13 articles about NONAFLUORO-1-BUTANESULFONYL CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.6%

perfluorobutanesulfonic acid (375-73-5,59933-66-3) → 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonyl chloride (2991-84-6)

Guidance literature:

With phosphorus pentachloride; at 100 ℃;

DOI:10.1016/S0022-1139(00)82346-5

Reference yield: 83.0%

C4F9O2S(1-)*Cl(1-)*Mg(2+) → 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonyl chloride (2991-84-6)

Guidance literature:

In dichloromethane; water; chlorination at 5-10°C;

Reference yield: 82.0%

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane (423-39-2) + rongalite (149-44-0) → 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonyl chloride (2991-84-6)

Guidance literature:

With chlorine; In N-methyl-acetamide; water;

upstream raw materials:

nonafluorobutanesulfinic acid

perfluorobutanesulfonic acid

sodium 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfinate

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

Downstream raw materials:

methyl 3-methoxy-2-(perfluoro-1-butanesulfonyloxy)benzoate

methyl 4-methoxy-2-(perfluoro-1-butanesulfonyloxy)benzoate

Refernces

• 1、 Conte, L.,Napoli, M.,Scipioni, A.,Guerrato, A.. "A NEW METHOD FOR RECOVERING WASTE ALKALINE PERFLUORO-n-BUTANESULFONATE". . p. 277 - 283. Retrieved 1991.
• 2、 Scott, Peter J.H.,Campbell, Ian B.,Steel, Patrick G.. "A general method for the preparation of perfluoroalkanesulfonyl chlorides". . p. 1196 - 1201. Retrieved 2007/10/03.
• 3、 -. "Preparation of 2-chloro-5-methyl-pyridine". . . Retrieved 2008/06/13.