8-Quinolyl methacrylate

Base Information

• Chemical Name: 8-Quinolyl methacrylate
• CAS No.: 19352-51-3
• Molecular Formula: C13H11NO2
• Molecular Weight: 213.236
• Hs Code.: 2933499090
• European Community (EC) Number: 242-982-5
• UNII: TXA6F6SH66
• DSSTox Substance ID: DTXSID60172959
• Nikkaji Number: J242.778H
• Wikidata: Q83043046
• Mol file: 19352-51-3.mol

Synonyms:8-Quinolyl methacrylate;19352-51-3;quinolin-8-yl methacrylate;quinolin-8-yl 2-methylprop-2-enoate;8-quinolinyl methacrylate;TXA6F6SH66;EINECS 242-982-5;UNII-TXA6F6SH66;SCHEMBL2839930;DTXSID60172959;Methacrylic acid 8-quinolyl ester;2-Propenoicacid,2-methyl-,8-quinolinyl ester;2-Propenoic acid, 2-methyl-, 8-quinolinyl ester

Chemical Property of 8-Quinolyl methacrylate

Chemical Property:

• Vapor Pressure: 1.29E-05mmHg at 25°C
• Refractive Index: 1.599
• Boiling Point: 368.2 °C at 760 mmHg
• Flash Point: 176.5 °C
• PSA: 39.19000
• Density: 1.169 g/cm³
• LogP: 2.71630
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 213.078978594
• Heavy Atom Count: 16
• Complexity: 288

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OC1=CC=CC2=C1N=CC=C2

Technology Process of 8-Quinolyl methacrylate

There total 3 articles about 8-Quinolyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

8-quinolinol (148-24-3,24804-14-6) + Methacryloyl chloride (920-46-7,26937-45-1) → 8-methacroyloxyquinoline (19352-51-3)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1080/15421406.2020.1859704

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → 8-methacroyloxyquinoline (19352-51-3)

Guidance literature:

With PPA; at 120 - 125 ℃; for 3h;

Reference yield:

→ 8-methacroyloxyquinoline (19352-51-3)

Guidance literature:

8-Chinolinol, Methacryloylchlorid, NaOH;

DOI:10.1007/BF00957370

upstream raw materials:

8-quinolinol

poly(methacrylic acid)

Methacryloyl chloride

Refernces

• 1、 Kirienko et al.. "". . . Retrieved 1969.
• 2、 Merchant, J. R.,Pathare, P. M.. "Synthesis of Pyranoquinolines". . p. 786 - 787. Retrieved 2007/10/02.