2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester

Base Information

• Chemical Name: 2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester
• CAS No.: 86261-90-7
• Molecular Formula: C₉H₁₄N₂O₃
• Molecular Weight: 198.222
• Hs Code.: 2933990090
• European Community (EC) Number: 289-214-5
• DSSTox Substance ID: DTXSID0074635
• Nikkaji Number: J333.945I
• Wikidata: Q82002894
• Mol file: 86261-90-7.mol

Synonyms:86261-90-7;2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester;2-(2-OXO-1-IMIDAZOLIDINYL)ETHYL METHACRYLATE;2-(2-oxoimidazolidin-1-yl)ethyl 2-methylprop-2-enoate;2-(2-Oxoimidazolidin-1-yl)ethyl methacrylate;EINECS 289-214-5;EC 289-214-5;2-Imidazolidinone, 1-(2-methacryloxyethyl)methacryloxyethylethylene urea;SCHEMBL138215;DTXSID0074635;MFCD00192374;AKOS028111606;N-(methacryloxyethyl) imidazolidin-2-one;SY274850;FT-0694400;1-[2-(Methacryloyloxy)ethyl]imidazolidine-2-one;2-(2-oxoimidazolidin-1-yl)ethyl 2-methylacrylate;A841594;2-(2-oxoimidazolidinyl)ethyl 2-methylprop-2-enoate;W-111682;2-(2-oxidanylideneimidazolidin-1-yl)ethyl 2-methylprop-2-enoate;2-methyl-2-propenoic acid 2-(2-oxo-1-imidazolidinyl)ethyl ester

Chemical Property of 2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester

Chemical Property:

• Vapor Pressure: 8.64E-07mmHg at 25°C
• Melting Point: -30oC
• Refractive Index: n20/D 1.437
• Boiling Point: 405.6°Cat760mmHg
• PKA: 14.27±0.20(Predicted)
• Flash Point: 199.1°C
• PSA: 58.64000
• Density: 1.137g/cm³
• LogP: 0.39760
• Water Solubility.: 1000g/L at 20℃
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 198.10044231
• Heavy Atom Count: 14
• Complexity: 263

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s): F,C,Xn
• Hazard Codes: F,C,Xn
• Statements: 11-34-42/43-43-36/37/38-22
• Safety Statements: 16-26-33-36/37/39-45-46-36/37-24

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCN1CCNC1=O

Technology Process of 2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester

There total 3 articles about 2-Propenoic acid, 2-methyl-, 2-(2-oxo-1-imidazolidinyl)ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.3%

2-oxo-imidazolidine-1-ethanol (3699-54-5) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → N-(2-methacryloyloxyethyl)-N'-(methacryloyl) ethylene urea + 2-(2-oxoimidazolidinyl)ethyl 2-methylprop-2-enoate (86261-90-7)

Guidance literature:

With TEMPOL; oxygen; di(n-butyl)tin oxide; at 48 - 115 ℃; for 16.1667h; under 760.051 Torr; Product distribution / selectivity; Heating / reflux;

Reference yield: 81.0%

2-oxo-imidazolidine-1-ethanol (3699-54-5) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-(2-oxoimidazolidinyl)ethyl 2-methylprop-2-enoate (86261-90-7)

Guidance literature:

With TEMPOL; oxygen; lithium hydroxide; at 70 - 115 ℃; for 5.25h; under 760.051 Torr; Product distribution / selectivity; Heating / reflux;

Reference yield: 52.9%

2-hydroxyethylethyleneurea (161663-36-1) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-methyl-3-[2-(2-oxo-imidazolidin-1-yl)-ethoxy]-propionic acid + 2-methyl-3-[3-[2-(methacryloylamino)ethyl]-2-oxo-imidazolidin-1-yl]-propionic acid + N-[2-[3-methacryloyl-2-oxo-imidazolidin-1-yl]-ethyl]-methacrylamide + N-[2-(2-oxo-imidazolidin-1-yl)-ethyl]-methacrylamide (3089-19-8) + 2-(2-oxoimidazolidinyl)ethyl 2-methylprop-2-enoate (86261-90-7)

Guidance literature:

With 5A molecular sieve; Novozym 435 (immobilized lipase from Candida antarctica B); at 40 ℃; for 72h; Product distribution / selectivity;

upstream raw materials:

2-oxo-imidazolidine-1-ethanol

methacrylic acid methyl ester

2-hydroxyethylethyleneurea

Refernces

• 1、 -. "TRANSESTERIFICATION PROCESS". Page/Page column 9-10. . Retrieved 2013/09/26.
• 2、 -. "Transesterification process for production of (meth)acrylate ester monomers". Page/Page column 10-11. . Retrieved 2008/06/13.