oxalic acid, cerium salt

Base Information

• Chemical Name: oxalic acid, cerium salt
• CAS No.: 7047-99-6
• Molecular Formula: C2H2 O4 . x Ce
• Molecular Weight: 544.299
• Mol file: 7047-99-6.mol

Synonyms:Ceriumoxalate (6CI,7CI); Ethanedioic acid, cerium salt (9CI); Oxalic acid, ceriumsalt (8CI)

Chemical Property of oxalic acid, cerium salt

Chemical Property:

• Vapor Pressure: 1.02E-11mmHg at 25°C
• Boiling Point: 539.8°C at 760 mmHg
• Flash Point: 280.2°C
• PSA: 80.26000
• Density: 1.421g/cm³
• LogP: -3.51380

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxalic acid, cerium salt

There total 8 articles about oxalic acid, cerium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cerium oxalate decahydrate (6003-86-7,7100-55-2,10171-47-8,13266-83-6,15053-73-3,15750-47-7,35586-22-2) → cerium(III) oxalate (7047-99-6)

Guidance literature:

In neat (no solvent); at 250 ℃;

DOI:10.1002/bkcs.11398

Reference yield:

2Na(1+)*2CO2(1-)=(COONa)2 + cerium(III) chloride heptahydrate → cerium(III) oxalate (7047-99-6)

Guidance literature:

With glycine; In water;

DOI:10.1166/jnn.2017.13744

Reference yield:

oxalic acid (144-62-7,97993-78-7) + cerous nitrate → cerium(III) oxalate (7047-99-6)

Guidance literature:

With nitric acid; In water; Addn. of the solns. at 30°C with vigorous stirring in the order of oxalic acid, nitric acid, rare earth nitrate, distd. water.;

upstream raw materials:

oxalic acid

oxalate dianion

cerium oxalate decahydrate

Refernces

• 1、 Uwamino, Y.,Ishizuka, T.,Yamatera, H.. "". . p. 67 - 78. Retrieved 1984.
• 2、 Zhao, Pu Su,Gao, Xiu Mei,Zhu, Feng Xia,Hu, Xin Ming,Zhang, Li Li. "Ultrasonic-assisted solution-phase synthesis and property studies of hierarchical layer-by-layer mesoporous CeO2". . p. 375 - 380. Retrieved 2018/02/13.