Trioctylstannanylium;acetate

Base Information

• Chemical Name: Trioctylstannanylium;acetate
• CAS No.: 919-28-8
• Molecular Formula: C26H54 O2 Sn
• Molecular Weight: 517.424
• Mol file: 919-28-8.mol

Synonyms:SCHEMBL2695510

Chemical Property of Trioctylstannanylium;acetate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 26.30000
• Density: g/cm³
• LogP: 9.57650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 21
• Exact Mass: 518.314584
• Heavy Atom Count: 29
• Complexity: 214

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC[Sn+](CCCCCCCC)CCCCCCCC.CC(=O)[O-]

Technology Process of Trioctylstannanylium;acetate

There total 16 articles about Trioctylstannanylium;acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.4%

tri-n-octyl(phenyl)stannane (143363-50-2) + potassium acetate (127-08-2) → trioctyltin acetate (919-28-8)

Guidance literature:

tri-n-octyl(phenyl)stannane; With iodine; In methanol; at 65 ℃;

potassium acetate; In methanol; for 5h; Heating;

Reference yield:

i-Amyl alcohol (123-51-3) + carbon dioxide (124-38-9,18923-20-1) + di-(n-octyl)-bis-(3-methylbutoxy) tin (952316-32-4) + acetic anhydride (108-24-7) → 1,2-bis(acetyloxy)dioctylstannane (17586-94-6) + diisoamyl carbonate (2050-95-5) + trioctyltin acetate (919-28-8)

Guidance literature:

i-Amyl alcohol; carbon dioxide; di-(n-octyl)-bis-(3-methylbutoxy) tin; 1,1,3,3-tetraoctyl-1,3-bis(3-methylbutyloxy)distannoxane; at 120 ℃; under 30003 Torr;

acetic anhydride; at 25 ℃; for 1h; Product distribution / selectivity; Inert atmosphere;

Reference yield:

i-Amyl alcohol (123-51-3) + carbon dioxide (124-38-9,18923-20-1) + di-(n-octyl)-bis-(3-methylbutoxy) tin (952316-32-4) + acetic anhydride (108-24-7) + acetic acid (64-19-7,77671-22-8) → 1,2-bis(acetyloxy)dioctylstannane (17586-94-6) + diisoamyl carbonate (2050-95-5) + trioctyltin acetate (919-28-8)

Guidance literature:

i-Amyl alcohol; carbon dioxide; di-(n-octyl)-bis-(3-methylbutoxy) tin; 1,1,3,3-tetraoctyl-1,3-bis(3-methylbutyloxy)distannoxane; at 120 ℃; under 30003 Torr;

acetic anhydride; acetic acid; at 25 ℃; for 1h; Product distribution / selectivity; Inert atmosphere;

upstream raw materials:

tetraoctyltin

i-Amyl alcohol

carbon dioxide

di-(n-octyl)-bis-(3-methylbutoxy) tin

Downstream raw materials:

1,3-bis(acetyloxy)tetraoctyldistannoxane

1,2-bis(acetyloxy)dioctylstannane

3-methyl-1-butyl acetate

di-(n-octyl)-bis-(3-methylbutoxy) tin

Refernces

• 1、 -. "Recycling of organotin compounds". . . Retrieved 2013/12/02.
• 2、 -. "Process for Production of Alkyl Tin Alkoxide Compound, and Process for Production of Carbonic Acid Ester Using the Compound". Page/Page column 51. . Retrieved 2010/12/18.