Dichloroplatinum;dimethyl(phenyl)phosphanium

Base Information

• Chemical Name: Dichloroplatinum;dimethyl(phenyl)phosphanium
• CAS No.: 15393-14-3
• Molecular Formula: C16H22 Cl2 P2 Pt
• Molecular Weight: 542.284
• NSC Number: 162931
• Mol file: 15393-14-3.mol

Synonyms:15393-14-3;NSC162931;SCHEMBL1629102;NSC-162931

Chemical Property of Dichloroplatinum;dimethyl(phenyl)phosphanium

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 543.037824
• Heavy Atom Count: 21
• Complexity: 194

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[PH+](C)C1=CC=CC=C1.C[PH+](C)C1=CC=CC=C1.Cl[Pt]Cl

Technology Process of Dichloroplatinum;dimethyl(phenyl)phosphanium

There total 39 articles about Dichloroplatinum;dimethyl(phenyl)phosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Pt(P(C6H5)(CH3)2)4(2+)*PtCl4(2-)=[Pt(P(C6H5)(CH3)2)4][PtCl4] (79019-55-9,77070-30-5) → cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3)

Guidance literature:

In neat (no solvent); isothermal heating at 125-130°C for 2 h; monitoring by differential thermal anal.; elem. anal.;

Reference yield: 90.0%

{Pt2Cl2(TeC6H4OCH3)2(P(CH3)2C6H5)2} → cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3)

Guidance literature:

In chloroform; 20 h reflux; solvent removed under reduced pressure, residue dissolved in CDCl3, detected by 31P NMR;

DOI:10.1016/0022-328X(91)80220-E

Reference yield: 90.0%

tetrakis(dimethylphenylphosphine)platinum(0) (33361-89-6) + chloro-methylsulfanyl-methane (2373-51-5) → cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3)

Guidance literature:

In benzene; soln. of educts, reflux, 3h, concd. up, addn. of hexane; under N2; ppt. recrystd. from CH2Cl2/C6H14; elem. anal.;

DOI:10.1016/S0022-328X(00)99112-5

upstream raw materials:

sym-trans-{Pt₂Cl₄(P(C₄H₉)3)2}

Dimethyl(phenyl)phosphine

Pt(P(C₆H₅)(CH₃)2)4⁽²⁺⁾*PtCl₄^(2-)=[Pt(P(C₆H₅)(CH₃)2)4][PtCl₄]

tetrakis(dimethylphenylphosphine)platinum⁽⁰⁾

Downstream raw materials:

{PtCl(PMe₂Ph)3}{PF₆}

cis-Pt(disulphurdinitido)(PMe₂Ph)2

cis-Pt(thionylimino)2(PMe₂Ph)2

Pt(P(CH₃)2C₆H₅)2(SCCN)2

Refernces

• 1、 Bould, Jonathan,Base, Tomas,Londesborough, Michael G. S.,Oro, Luis A.,MacIas, Ramon,Kennedy, John D.,Kubat, Pavel,Fuciman, Marcel,Polivka, Tomas,Lang, Kamil. "Reversible capture of small molecules on bimetallaborane clusters: Synthesis, structural characterization, and photophysical aspects". . p. 7511 - 7523. Retrieved 2011/10/03.
• 2、 Burchell, Colin J.,Aucott, Stephen M.,Slawin, Alexandra M. Z.,Woollins, J. Derek. "Synthesis and characterisation of triselenocarbonate [CSe3] 2- complexes". . p. 735 - 739. Retrieved 2007/10/03.