Boron monochloride monofluoride

Base Information

• Chemical Name: Boron monochloride monofluoride
• CAS No.: 22395-93-3
• Molecular Formula: BCl F
• Molecular Weight: 65.2624
• DSSTox Substance ID: DTXSID10176922
• Wikidata: Q83047254
• Mol file: 22395-93-3.mol

Synonyms:Boron monochloride monofluoride;22395-93-3;ClBF;Chlorofluoroborane;DTXSID10176922

Chemical Property of Boron monochloride monofluoride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 64.9765610
• Heavy Atom Count: 3
• Complexity: 4.8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B](F)Cl

Technology Process of Boron monochloride monofluoride

There total 2 articles about Boron monochloride monofluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

boron fluoride (13768-60-0) + chlorine (7782-50-5) → ClBF (22395-93-3) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2)

Guidance literature:

In gas; 294 K and between 295 and 881 K, He and Ar as diluent gas, pressure was between 1.6 and 8.3 Torr; detected by fluorescence spectroscopy on basis of BF; Kinetics;

DOI:10.1021/j100269a036

Reference yield:

(OC)B(BF2)3 (37170-77-7) + boron trichloride (10294-34-5) → boron dichloride (13842-52-9) + ClBF (22395-93-3) + (Cl2B)3BCO (326609-53-4) + (F2B)(ClFB)(Cl2B)BCO (444109-63-1) + boron difluoride (13842-55-2)

Guidance literature:

In neat (no solvent); at 0°C for 50 min, further products; cooled to -70°C, evapd.(vac), dissolved (CD2Cl2), NMR;

DOI:10.1016/S0277-5387(01)01032-4

upstream raw materials:

boron fluoride

chlorine

(OC)B(BF₂)3

boron trichloride

Refernces

• 1、 Light, G. C.,Herm, R. R.,Matsumoto, J. H.. "Kinetics of Some Gas-Phase Elementary Reactions of Boron Monofluoride". . p. 5066 - 5074. Retrieved 2007/10/02.