DESMETHYL-FORMAMIDO-PIRIMICARB

Base Information

• Chemical Name: DESMETHYL-FORMAMIDO-PIRIMICARB
• CAS No.: 27218-04-8
• Molecular Formula: C11H16 N4 O3
• Molecular Weight: 252.273
• Hs Code.: 2933599090
• Mol file: 27218-04-8.mol

Synonyms:Carbamicacid, dimethyl-, 2-(formylmethylamino)-5,6-dimethyl-4-pyrimidinyl ester (9CI);Carbamic acid, dimethyl-, ester withN-(4-hydroxy-5,6-dimethyl-2-pyrimidinyl)-N-methylformamide (8CI); Formamide,N-(4-hydroxy-5,6-dimethyl-2-pyrimidinyl)-N-methyl-, dimethylcarbamate (ester)(8CI); 2-N-Methylformamido-5,6-dimethyl-4-pyrimidinyl dimethylcarbamate;Pirimicarb II

Chemical Property of DESMETHYL-FORMAMIDO-PIRIMICARB

Chemical Property:

• Vapor Pressure: 4.66E-07mmHg at 25°C
• Boiling Point: 413.8°Cat760mmHg
• PKA: 3.52±0.10(Predicted)
• Flash Point: 204.1°C
• PSA: 75.63000
• Density: 1.229g/cm³
• LogP: 1.38230
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Desmethyl-formamido-pirimicarb ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 25-50/53
• Safety Statements: 45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of DESMETHYL-FORMAMIDO-PIRIMICARB

There total 2 articles about DESMETHYL-FORMAMIDO-PIRIMICARB which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pirimicarb (23103-98-2) → 2-(methylamino)-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (30614-22-3) + 2‐methylamino‐5,6‐dimethyl‐4‐hydroxypyrimidine + 2-<(methylformyl)amino>-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (27218-04-8) + 2-(formylamino)-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (178273-91-1) + 2‐dimethylamino‐5,6‐dimethyl‐4‐hydroxypyrimidine (40778-16-3)

Guidance literature:

With titanium(IV) oxide; In water; for 0.5h; pH=7.1; Reagent/catalyst; Kinetics; UV-irradiation;

DOI:10.1016/j.jphotochem.2014.10.014

Reference yield:

pirimicarb (23103-98-2) → 2-(amino)-5,6-dimethylpyrimidin-4-yldimethylcarbamate (30614-21-2) + 2-(methylamino)-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (30614-22-3) + 2-<(methylformyl)amino>-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (27218-04-8) + 2-(formylamino)-5,6-dimethylpyrimidin-4-yl dimethylcarbamate (178273-91-1) + 2‐dimethylamino‐5,6‐dimethyl‐4‐hydroxypyrimidine (40778-16-3)

Guidance literature:

With phosphate buffer; In water; Rate constant; Quantum yield; Mechanism; Irradiation; var. wavelengths and time;

DOI:10.1021/jf9501711

upstream raw materials:

pirimicarb

Refernces

• 1、 Pirisi, Filippo M.,Cabras, Paolo,Garau, V. Luigi,Melis, Marinella,Secchi, Enrico. "Photodegradation of Pesticides. Photolysis Rates and Half-Life of Pirimicarb and Its Metabolites in Reactions in Water and in Solid Phase". . p. 2417 - 2422. Retrieved 2007/10/03.