di-tert-butyl peroxyoxalate

Base Information

• Chemical Name: di-tert-butyl peroxyoxalate
• CAS No.: 1876-22-8
• Molecular Formula: C10H18 O6
• Molecular Weight: 234.249
• Mol file: 1876-22-8.mol

Synonyms:Ethanediperoxoicacid, bis(1,1-dimethylethyl) ester (9CI); Peroxyoxalic acid, di-tert-butylester (6CI,7CI,8CI); Di-tert-butyl diperoxyoxalate; Di-tert-butyl peroxalate;Di-tert-butyl peroxyoxalate; tert-Butyl peroxalate

Chemical Property of di-tert-butyl peroxyoxalate

Chemical Property:

• Vapor Pressure: 0.0441mmHg at 25°C
• Boiling Point: 237.7°Cat760mmHg
• Flash Point: 93.7°C
• PSA: 71.06000
• Density: 1.097g/cm³
• LogP: 1.53300

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of di-tert-butyl peroxyoxalate

There total 3 articles about di-tert-butyl peroxyoxalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tert.-butylhydroperoxide (75-91-2) + oxalyl dichloride (79-37-8) → di-tert-butyl diperoxyoxalate (1876-22-8)

Guidance literature:

With pyridine; In decane; hexane; at -5 - 15 ℃;

DOI:10.1002/chem.201903392

Reference yield: 45.0%

tert.-butylhydroperoxide (75-91-2) + oxalic dichloride (79-37-8) → di-tert-butyl diperoxyoxalate (1876-22-8)

Guidance literature:

With pyridine; In Petroleum ether; for 0.5h;

DOI:10.1002/1520-6017(200012)89:12<1518::AID-JPS2>3.0.CO;2-O

Reference yield:

→ di-tert-butyl diperoxyoxalate (1876-22-8)

Guidance literature:

Oxalylchlorid, t-Butylhydroperoxid;

DOI:10.1021/ja01492a054

upstream raw materials:

tert.-butylhydroperoxide

oxalyl dichloride

oxalic dichloride

Downstream raw materials:

2-(2-tert-butoxy-1-phenylethoxy)-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole

2-methoxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole

Naphthalene-1-carboxylic acid 1-(2-tert-butoxy-1-phenyl-ethoxy)-2,2,6,6-tetramethyl-piperidin-4-yl ester

2-allyloxy-1,1,3,3-tetramethyl-1,3-dihydroisoindole

Refernces

• 1、 Nukaya,Inaoka,Ishida,Tsuji,Suwa,Wakabayashi,Kosuge. "Modification of the amino group of guanosine by methylglyoxal and other α-ketoaldehydes in the presence of hydrogen peroxide". . p. 649 - 653. Retrieved 1993.
• 2、 Abdallah, Dalia,Ghani, Mohmad Asri Abd,Cunningham, Michael F.,Kazmaier, Peter M.,Keoshkerian, Barkev,Buncel, Erwin. "Multi-armed, TEMPO-functionalized unimolecular initiators for starburst dendrimer synthesis via stable free radical polymerization. 1. Tri azo-functionalized unimer". . p. 1393 - 1402. Retrieved 2007/10/03.
• 3、 Haire, D. Lawrence,Janzen, Edward G.,Hrvoic, Ivan. "ESR of new β-phosphorus nitroxides from aldo- and keto-nitrones". . p. 767 - 773. Retrieved 2007/10/03.