L-Idose

Base Information

• Chemical Name: L-Idose
• CAS No.: 5934-56-5
• Molecular Formula: C6H12 O6
• Molecular Weight: 180.158
• Hs Code.: 2940000080
• European Community (EC) Number: 227-688-7
• Nikkaji Number: J902.721A
• Wikipedia: Idose
• Wikidata: Q106055904
• Mol file: 5934-56-5.mol

Synonyms:idopyranose;idose;idose, (alpha-D)-isomer;idose, (L)-isomer;idose, 14C-labeled, (alpha-D)-isomer

Chemical Property of L-Idose

Chemical Property:

• Vapor Pressure: 2.59E-13mmHg at 25°C
• Boiling Point: 527.1°C at 760 mmHg
• PKA: 12.45±0.20(Predicted)
• Flash Point: 286.7°C
• PSA: 110.38000
• Density: 1.581g/cm³
• LogP: -3.22140
• Storage Temp.: Refrigerator
• Solubility.: Methanol (Slightly), Water (Soluble)
• XLogP3: -2.6
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 180.06338810
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

98%, ^*data from raw suppliers

L-Idose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)O)O)O)O)O
• Isomeric SMILES: C([C@H]1[C@H]([C@@H]([C@H](C(O1)O)O)O)O)O
• Uses: L-Isomer of D-Idose (I175050), a monosaccharide that has is an important component of dermatan sulfate and heparan sulfate.

Technology Process of L-Idose

There total 132 articles about L-Idose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

L-gulose (6027-89-0) → L-sorbose (87-79-6,18875-34-8) + L-tagatose (17598-82-2,18875-34-8) + glucose (5934-56-5)

Guidance literature:

L-gulose; With aluminum oxide; In pyridine; for 2h; Heating;

With sulfuric acid; In acetone; for 2h; Further stages.;

DOI:10.1016/j.carres.2007.05.033

Reference yield:

D-galactitol (608-66-2) + water (7732-18-5) → lyxo-2-hexulose (57-48-7,87-79-6,87-81-0,551-68-8,3615-39-2,3615-56-3,6035-50-3,7776-48-9,16354-64-6,17598-81-1,17598-82-2,23140-52-5,30237-26-4,65732-90-3,73952-10-0,73952-11-1,139686-85-4,18875-34-8) + galactose (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5) + galactonic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6)

Guidance literature:

at 80 ℃; weitere Produkte:2-Keto-DL-galaktonsaeure; DL-Galakturonsaeure;Schleimsaeure;

DOI:10.1021/ja01276a001

Reference yield:

galactonic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6) → galactose (50-99-7,59-23-4,921-60-8,1949-88-8,1990-29-0,2152-76-3,2595-97-3,2595-98-4,3458-28-4,4205-23-6,5934-56-5,5978-95-0,5987-68-8,6027-89-0,6038-51-3,7635-11-2,10030-80-5,15572-79-9,19163-87-2,23567-25-1,26566-61-0,30077-17-9,31103-86-3,39665-52-6,40866-07-7,58367-01-4,58407-05-9,58407-06-0,83198-69-0,83198-70-3,83198-71-4,93780-23-5,145920-48-5)

Guidance literature:

das Lacton regiert;

upstream raw materials:

6,7-dideoxy-L-ido-hept-6-enitol

5,6-anhydro-1,2-O-isopropylidene-β-L-idofuranose

1,2-O-isopropylidene-β-L-idofuranose

((2S,3R,4S,5R)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol

Downstream raw materials:

o-nitrothiophenol

p-benzosemiquinone radical anion

succinic acid

L-Lactic acid

Refernces

• 1、 Blanc-Muesser,Defaye. "". . p. 568. Retrieved 1977.
• 2、 Qin, Ze,Zhang, Jin,Chen, Liang,Liu, Shu-Xiang,Zhao, Hai-Feng,Mao, Hui-Min,Zhang, Hong-Yang,Li, De-Fang. "Anti-inflammatory active components of the roots of Datura metel". . p. 392 - 398. Retrieved 2020/03/30.
• 3、 Stovbun,Skoblin,Zanin,Tverdislov,Taran,Parmon. "Formation of Chiral Structures in Photoinitiated Formose Reaction". . p. 108 - 116. Retrieved 2018/04/05.