Tetradeca-9,12-dien-1-OL

Base Information

• Chemical Name: Tetradeca-9,12-dien-1-OL
• CAS No.: 51937-00-9
• Molecular Formula: C₁₄H₂₆O
• Molecular Weight: 210.36
• European Community (EC) Number: 257-527-6
• DSSTox Substance ID: DTXSID10860637
• Mol file: 51937-00-9.mol

Synonyms:9,12-Tetradecadien-1-ol, (9E,12Z)-;51937-00-9;42521-46-0;DTXSID10860637;TETRADECA-9,12-DIEN-1-OL;FT-0674950

Chemical Property of Tetradeca-9,12-dien-1-OL

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 5.31E-05mmHg at 25°C
• Refractive Index: 1.473
• Boiling Point: 310.6 °C at 760 mmHg
• PKA: 15.20±0.10(Predicted)
• Flash Point: 112.3 °C
• PSA: 20.23000
• Density: 0.86 g/cm³
• LogP: 4.23180
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 210.198365449
• Heavy Atom Count: 15
• Complexity: 159

Purity/Quality:

98%Min ^*data from raw suppliers

(9E,12Z)-9,12-Tetradecadienol ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCC=CCCCCCCCCO
• Uses: Z,E-9,12-TETRADECADIEN-1-OL is used as insect attractant. The sex pheromone of Plodia interpunctella used as insect attractants.

Technology Process of Tetradeca-9,12-dien-1-OL

There total 41 articles about Tetradeca-9,12-dien-1-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-<(tetrahydro-2H-pyran-2-yl)oxy> 9Z, 12E-tetradecadiene (112464-06-9) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With toluene-4-sulfonic acid; In methanol; for 2h; Heating;

DOI:10.1007/BF00598272

Reference yield: 85.0%

(E)-Tetradec-12-en-9-yn-1-ol (42521-44-8) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With hydrogen; P-2 Ni; In ethanol; at 25 ℃;

DOI:10.1007/bf02757427

Reference yield: 71.0%

Tetradec-9Z,12E-dien-1-yl Acetate (30507-70-1) → Tetradeca-cis-9,trans-12-dien-1-ol (42521-46-0,51937-00-9)

Guidance literature:

With sodium hydroxide; In methanol;

upstream raw materials:

[1-(8-tetrahydropyran-2-yloxy-octyl)-hexa-2t,4t-dienyl]-phosphonic acid diethyl ester

2-[((9E,12E)-Tetradeca-9,12-dienyl)oxy]-tetrahydro-pyran

2-(8-bromooctyloxy)tetrahydropyran

Sorbyl alcohol

Refernces

• 1、 Herbert, Myles B.,Marx, Vanessa M.,Pederson, Richard L.,Grubbs, Robert H.. "Concise syntheses of insect pheromones using Z-Selective cross metathesis". supporting information. p. 310 - 314. Retrieved 2013/02/23.
• 2、 Hornyanszky, Gabor,Rohaly, Janos,Novak, Lajos. "Facile synthesis of mill moth's sex pheromone components". . p. 1533 - 1540. Retrieved 2008/09/20.