Glycidyl butyrate

Base Information

• Chemical Name: Glycidyl butyrate
• CAS No.: 2461-40-7
• Molecular Formula: C7H12O3
• Molecular Weight: 144.17
• Mol file: 2461-40-7.mol

Synonyms:Butanoicacid, oxiranylmethyl ester (9CI);Butyric acid, 2,3-epoxypropyl ester(6CI,7CI,8CI);(?à)-Glycidylbutyrate;2-Oxiranylmethyl butyrate;Glycidyl butanoate;Glycidyl butyrate;Glydicyl butyrate;NSC 83144;

Chemical Property of Glycidyl butyrate

Chemical Property:

• Vapor Pressure: 0.402mmHg at 25°C
• Refractive Index: 1.444
• Boiling Point: 196.258 °C at 760 mmHg
• Flash Point: 85 °C
• PSA: 38.83000
• Density: 1.069 g/cm³
• LogP: 0.72850

Purity/Quality:

99.9% ^*data from raw suppliers

GlycidylButyrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Glycidyl butyrate

There total 6 articles about Glycidyl butyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

sodium butyrate (156-54-7) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → (+/-)-glycidyl butyrate (2461-40-7)

Guidance literature:

at 60 ℃; for 8h;

DOI:10.2174/157017811795371412

Reference yield: 70.0%

potassium n-butyrate (589-39-9) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → (+/-)-glycidyl butyrate (2461-40-7)

Guidance literature:

With tetrabutylammomium bromide; In toluene; for 5h; Solvent; Reflux;

DOI:10.1016/j.tetlet.2015.02.046

Reference yield:

oxiranyl-methanol (556-52-5) + butyryl chloride (141-75-3) → (+/-)-glycidyl butyrate (2461-40-7)

Guidance literature:

With triethylamine; In toluene; at 0 ℃; for 0.833333h;

upstream raw materials:

sodium butyrate

epichlorohydrin

oxiranyl-methanol

butyryl chloride

Downstream raw materials:

allyl butyrate

(R)-glycidyl butyrate

(R)-oxiranemethanol

(S)-oxiranemethanol

Refernces

• 1、 Huang, Qiang,Meng, Qingyi,Ban, Chunlan,Zhang, Rui,Gao, Yingyu. "Study of liquid–solid catalytic reaction of epichlorohydrin with sodium butyrate in the presence of tetrabutylammonium bromide". . p. 1552 - 1556. Retrieved 2016.
• 2、 Jiang, Chengjun,Yan, Jianbo. "Stereoselective synthesis of (R)-glycidyl butyrate from racemic glycidyl butyrate or epichlorohydrin via hydrolytic kinetic resolution". scheme or table. p. 242 - 243. Retrieved 2012/05/19.