Methyltriethylstannane

Base Information

• Chemical Name: Methyltriethylstannane
• CAS No.: 2097-60-1
• Molecular Formula: C7H18Sn
• Molecular Weight: 220.93
• Hs Code.: 2931900090
• Mol file: 2097-60-1.mol

Synonyms:triethylmethyltin;Methyl-triethyl-stannan;Methyl triethyltin;Stannane,triethylmethyl;Methyl-triaethyl-zinn;Triethyl-methyl-stannan;triethyl-methyl-stannane;Methyltriethylstannane;Triaethyl-methyl-stannan;

Chemical Property of Methyltriethylstannane

Chemical Property:

• Vapor Pressure: 3.07mmHg at 25°C
• Boiling Point: 160.6°Cat760mmHg
• Flash Point: 44.9°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.24110

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyltriethylstannane

There total 9 articles about Methyltriethylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

diiodomethane (75-11-6) + diethylzinc (557-20-0) + triethylstannane (997-50-2) → tetraethyltin (597-64-8) + triethyl-methyl stannane (2097-60-1)

Guidance literature:

In toluene; reaction with Zn(C2H5)2; then addn. of CH2I2 in toluene at 0°C;;

DOI:10.1016/S0022-328X(00)86131-8

Reference yield: 46.1%

triethylstannane (997-50-2) + neodymium(III) hexamethyldisilazide → bis(2-methoxyethanolato)triethylstannylneodymium + triethyl-methyl stannane (2097-60-1) + hexaethyl distannane (993-63-5) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

In 1,2-dimethoxyethane; (vac.); soln. of Nd- and Sn-compd. was heated at 100°C for 20 h; solvent was replaced with hexane, Et3Sn-Pr compd. was isolated, elem. anal.; distn. afforded (Et3Sn)2; Et3SnMe was detected by GLC of the org. layer; hexamethyldisilazane was detected by GLC of the volatiles;

DOI:10.1016/S0022-328X(00)85913-6

Reference yield: 41.7%

triethylstannane (997-50-2) + tris(bis(trimethylsilyl)amido)praseodymium(III) → bis(2-methoxyethanolato)triethylstannylpraseodymium + triethyl-methyl stannane (2097-60-1) + hexaethyl distannane (993-63-5) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

In 1,2-dimethoxyethane; (vac.); soln. of Pr- and Sn-compd. was heated at 100°C for 20 h; solvent was replaced with hexane, Et3Sn-Pr compd. was isolated, elem. anal.; distn. afforded (Et3Sn)2; Et3SnMe was detected by GLC of the org. layer; hexamethyldisilazane was detected by GLC of the volatiles;

DOI:10.1016/S0022-328X(00)85913-6

upstream raw materials:

diiodomethane

diethylzinc

triethylstannane

chlorotriethylstannane

Downstream raw materials:

trimethylstannyl iodide

methyl iodide

triethyltin bromide

diethyl-methyl tin ⁽¹⁺⁾; bromide

Refernces

• 1、 Pollard,Nickless,Uden. "Chromatographic studies on group IVB elements. I. Redistribution reactions of the tetraalkyls.". . p. 28 - 56. Retrieved 2008/10/08.