9H-Fluoren-3-amine

Base Information

• Chemical Name: 9H-Fluoren-3-amine
• CAS No.: 6344-66-7
• Molecular Formula: C13H11N
• Molecular Weight: 181.2331
• Hs Code.: 2921499090
• NSC Number: 51316
• UNII: 64ZL3JSZ3A
• DSSTox Substance ID: DTXSID50212858
• Nikkaji Number: J3.087B
• Wikidata: Q83088072
• Mol file: 6344-66-7.mol

Synonyms:9H-Fluoren-3-amine;6344-66-7;3-Aminofluorene;FLUOREN-3-AMINE;CCRIS 6998;NSC 51316;BRN 1949565;64ZL3JSZ3A;NSC-51316;4-12-00-03387 (Beilstein Handbook Reference);NSC51316;AMINOFLUORENE, 3-;UNII-64ZL3JSZ3A;Oprea1_067063;Oprea1_306662;SCHEMBL2362632;DTXSID50212858;AKOS000200612;AS-54775;LS-69159;W10049;Z90125012

Chemical Property of 9H-Fluoren-3-amine

Chemical Property:

• Vapor Pressure: 1.71E-05mmHg at 25°C
• Melting Point: 152-153 °C
• Boiling Point: 364.2°Cat760mmHg
• PKA: 4.51±0.20(Predicted)
• Flash Point: 193.3°C
• PSA: 26.02000
• Density: 1.203g/cm³
• LogP: 3.42120
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 181.089149355
• Heavy Atom Count: 14
• Complexity: 213

Purity/Quality:

99% ^*data from raw suppliers

9H-Fluoren-3-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2=C(C=C(C=C2)N)C3=CC=CC=C31

Technology Process of 9H-Fluoren-3-amine

There total 8 articles about 9H-Fluoren-3-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3-nitro-9H-fluorene (5397-37-5) → 9H-fluoren-3-amine (6344-66-7)

Guidance literature:

With borane-ammonia complex; In methanol; water; at 20 ℃; for 0.0833333h;

DOI:10.1021/cs500167k

Reference yield:

3-amino-9-fluorenone (6276-05-7) → 9H-fluoren-3-amine (6344-66-7)

Guidance literature:

With potassium hydroxide; hydrazine hydrate; diethylene glycol;

DOI:10.1021/ja01612a069

Reference yield:

1,2,3,9a-Tetrahydro-fluorenon-(3)-oxim (7235-13-4) → 9H-fluoren-3-amine (6344-66-7)

Guidance literature:

With hydrogenchloride; acetic anhydride; In acetic acid;

DOI:10.1039/j39670000120

upstream raw materials:

3-nitro-9H-fluorene

2-bromo-3-nitro-fluorene

3-amino-9-fluorenone

N-fluoren-3-yl-diacetamide

Downstream raw materials:

N-(9H-fluoren-3-yl)acetamide

3-fluoro-9H-fluorene

3-hydroxyfluorene

Refernces

• 1、 Weisburger. "-". . p. 1914. Retrieved 1955.
• 2、 Zhao, Lixing,Hu, Chenyang,Cong, Xuefeng,Deng, Gongda,Liu, Liu Leo,Luo, Meiming,Zeng, Xiaoming. "Cyclic (Alkyl)(amino)carbene Ligand-Promoted Nitro Deoxygenative Hydroboration with Chromium Catalysis: Scope, Mechanism, and Applications". supporting information. p. 1618 - 1629. Retrieved 2021/01/25.
• 3、 Metin, ?nder,Mendoza-Garcia, Adriana,Dalmizrak, Di?dem,Gültekin, Mehmet Serdar,Sun, Shouheng. "FePd alloy nanoparticles assembled on reduced graphene oxide as a catalyst for selective transfer hydrogenation of nitroarenes to anilines using ammonia borane as a hydrogen source". . p. 6137 - 6143. Retrieved 2016/08/05.