10-hydroxyanthrone

Base Information

• Chemical Name: 10-hydroxyanthrone
• CAS No.: 549-99-5
• Molecular Formula: C14H10O2
• Molecular Weight: 210.232
• Hs Code.: 2914400090
• Mol file: 549-99-5.mol

Synonyms:10-Hydroxy-anthron;9-hydroxyanthron-10-one;oxanthrone;10-Hydroxy-9,10-dihydroanthracene-9-one;9,10-dihydro-9-oxoanthracene;9-hydroxy-10-anthraquinone;

Chemical Property of 10-hydroxyanthrone

Chemical Property:

• Vapor Pressure: 8.3E-07mmHg at 25°C
• Boiling Point: 390.8°Cat760mmHg
• Flash Point: 166.9°C
• PSA: 37.30000
• Density: 1.317g/cm³
• LogP: 2.31270

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-hydroxyanthrone

There total 11 articles about 10-hydroxyanthrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

9-nitroanthracene (602-60-8) → oxanthrone (549-99-5) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With formic acid; In acetonitrile; at 20 ℃; for 2h; Irradiation;

DOI:10.1016/j.tetlet.2007.12.075

Reference yield: 45.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + C18H18O3 → oxanthrone (549-99-5) + 9,10-phenanthrenequinone (84-65-1) + acetophenone (98-86-2)

Guidance literature:

With palladium diacetate; In acetonitrile; for 2h; Product distribution; Mechanism; Ambient temperature; also p-substituted styrenes; other ozonide and hydroperoxide;

DOI:10.1021/jo00224a081

Reference yield: 25.0%

9,10-epidioxy-9,10-dihydroanthracene (4741-24-6) → oxanthrone (549-99-5) + 9,10-phenanthrenequinone (84-65-1) + C19H15NO4 (55894-48-9,66964-85-0) + N-methylethano-9,10 dihydroxy-9,10 anthracenedicarboximide-11,12 (92755-93-6)

Guidance literature:

With N-methylmaleimide; In acetone; for 2.2h; Irradiation;

upstream raw materials:

styrene

9,10-epidioxy-9,10-dihydroanthracene

anthracene

water

Downstream raw materials:

9,10-Dihydroxyanthracene

anthracen-9(10H)-one

9,10-phenanthrenequinone

water

Refernces

• 1、 Diaz-Uribe, Carlos E.,Daza, Martha C.,Páez-Mozo, Edgar A.,Martínez O., Fernando,Guedes, Carmen L.B.,Di Mauro, Eduardo. "Visible light singlet oxygen production with tetra(4-carboxyphenyl) porphyrin/SiO2". . p. 47 - 52. Retrieved 2013/07/25.
• 2、 Cors, Ariel,Bonesi, Sergio M.,Erra-Balsells, Rosa. "Photoreduction of nitro arenes by formic acid in acetonitrile at room temperature". . p. 1555 - 1558. Retrieved 2008/09/19.