4-BENZOYL-4'-BROMOBIPHENYL

Base Information

• Chemical Name: 4-BENZOYL-4'-BROMOBIPHENYL
• CAS No.: 63242-14-8
• Molecular Formula: C19H13BrO
• Molecular Weight: 337.216
• Hs Code.: 2914700090
• Mol file: 63242-14-8.mol

Synonyms:4-Benzoyl-4'-bromobiphenyl;4-(4-Bromophenyl)benzophenone;Labotest-BB LT01143414;

Chemical Property of 4-BENZOYL-4'-BROMOBIPHENYL

Chemical Property:

• Appearance/Colour: Powder
• Melting Point: 157-161 °C(lit.)
• Boiling Point: 459.6 °C at 760 mmHg
• Flash Point: 64.1 °C
• PSA: 17.07000
• Density: 1.354 g/cm³
• LogP: 5.34710

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Benzoyl-4''-bromobiphenyl ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 4-BENZOYL-4'-BROMOBIPHENYL

There total 4 articles about 4-BENZOYL-4'-BROMOBIPHENYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

4-bromo-1,1'-biphenyl (92-66-0) + benzoyl chloride (98-88-4) → 4-benzoyl-4'-bromobiphenyl (63242-14-8)

Guidance literature:

With aluminium trichloride; In carbon disulfide; for 5h; Heating;

DOI:10.1016/S0223-5234(97)89856-X

Reference yield: 71.0%

4-Bromophenylboronic acid (5467-74-3) + benzoyl chloride (98-88-4) → (4-bromophenyl)(phenyl)methanone (90-90-4) + 4-benzoyl-4'-bromobiphenyl (63242-14-8)

Guidance literature:

With C₃₅H₃₅ClFeN₃O₂PPd; sodium hydrogencarbonate; In water; toluene; at 50 ℃; Inert atmosphere;

DOI:10.1021/om5006758

Reference yield: 8.0%

4-chlorobenzoyl chloride (586-75-4) + phenylboronic acid (98-80-6) → (4-bromophenyl)(phenyl)methanone (90-90-4) + 4-benzoyl-4'-bromobiphenyl (63242-14-8)

Guidance literature:

With C₄₂H₃₆ClFeN₂O₄PPdS*C₆H₁₅N; sodium carbonate; In water; toluene; at 50 ℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.organomet.6b00600

upstream raw materials:

4-bromo-1,1'-biphenyl

benzoyl chloride

1,4-bromoiodobenzene

4-Bromophenylboronic acid

Downstream raw materials:

4-bromo-4'-[hydroxyl(phenyl)methyl]biphenyl

3,6-bis(benzoylbiphenyl)ethynyl-9-tetradecylcarbazole

2-[2-(2-methoxyethoxy)ethoxy]ethyl 3,5-di(benzoylbiphenylethynyl)benzoate

t-butyl 3,5-di(benzoylbiphenylethynyl)benzoate

Refernces

• 1、 ?koch, Karel,Císa?ová, Ivana,?těpni?ka, Petr. "Synthesis of a polar phosphinoferrocene amidosulfonate ligand and its application in pd-catalyzed cross-coupling reactions of aromatic boronic acids and acyl chlorides in an aqueous medium". . p. 3378 - 3387. Retrieved 2016/10/21.
• 2、 -. "NON-RESONANT TWO-PHOTON ABSORPTION RECORDING MATERIAL AND NON-RESONANT TWO-PHOTON ABSORPTION COMPOUND". Page/Page column 26. . Retrieved 2013/02/27.