4,4'-Methylenebis(N-furfurylideneaniline)

Base Information

• Chemical Name: 4,4'-Methylenebis(N-furfurylideneaniline)
• CAS No.: 6264-59-1
• Molecular Formula: C23H18 N2 O2
• Molecular Weight: 354.408
• European Community (EC) Number: 228-424-3
• DSSTox Substance ID: DTXSID301220325
• Nikkaji Number: J211.493C
• Mol file: 6264-59-1.mol

Synonyms:4,4'-Methylenebis(N-furfurylideneaniline);6264-59-1;EINECS 228-424-3;4,4'-METHYLENEBIS[N-FURFURYLIDENEANILINE];SCHEMBL11586470;DTXSID301220325;4,4'-Methylenebis[N-(2-furanylmethylene)aniline];4,4'-Methylenebis[N-(2-furanylmethylene)benzenamine];Benzenamine, 4,4'-methylenebis(N-(2-furanylmethylene)-

Chemical Property of 4,4'-Methylenebis(N-furfurylideneaniline)

Chemical Property:

• Melting Point: 163-164 °C(Solv: benzene (71-43-2))
• Boiling Point: 537.9±50.0 °C(Predicted)
• PKA: 3.55±0.50(Predicted)
• Flash Point: 279.1oC
• PSA: 51.00000
• Density: 1.13±0.1 g/cm3(Predicted)
• LogP: 5.96460
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 354.136827821
• Heavy Atom Count: 27
• Complexity: 447

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=COC(=C1)C=NC2=CC=C(C=C2)CC3=CC=C(C=C3)N=CC4=CC=CO4

Technology Process of 4,4'-Methylenebis(N-furfurylideneaniline)

There total 2 articles about 4,4'-Methylenebis(N-furfurylideneaniline) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

furfural (98-01-1) + 4,4'-diamino diphenyl methane (101-77-9) → bis[4-benzylidene-furan-2'-yl]methane (6264-59-1)

Guidance literature:

In 1,4-dioxane; at 80 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c9ra06425g

Reference yield:

4,4'-bis[N-methyl(diethoxyphosphonyl)-1-(2-furyl)]diaminodiphenylmethane → bis[4-benzylidene-furan-2'-yl]methane (6264-59-1)

Guidance literature:

With sodium hydroxide; In ethanol; Reflux;

DOI:10.1080/10426507.2011.638349

Reference yield:

bis[4-benzylidene-furan-2'-yl]methane (6264-59-1) + ethanol (64-17-5) + nickel dichloride (83864-14-6) → [Ni2(bis[4-benzylidene-furan-2'-yl]methane)2](n)(Cl4*2C2H5OH)(n)

Guidance literature:

In ethanol; addn. of soln. of NiCl2 in EtOH to hot EtOH soln. of CH2(C6H4NCHC4H3O)2;stirring for 2 h at 70°C; pptn., filtration, washing with EtOH and drying in vac.; storage in desiccator over CaCl2/P4O10 for 2 weeks; elem. anal.;

DOI:10.1007/s10973-006-8281-z

upstream raw materials:

furfural

4,4'-diamino diphenyl methane

Refernces

• 1、 Kraicheva,Vodenicharova,Tashev,Tosheva,Tsacheva,Troev. "Synthesis and NMR characterization of two novel anthracene-derived BIS-aminophosphonates. Basic hydrolysis of some aminophosphonate derivatives". experimental part. p. 660 - 667. Retrieved 2012/06/01.