Technology Process of 1,1',1''-Methanetriyltris(2-methylbenzene)
There total 5 articles about 1,1',1''-Methanetriyltris(2-methylbenzene) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium tetrahydroborate; trifluoroacetic acid;
In
dichloromethane;
for 2.5h;
Cooling with ice;
- Guidance literature:
-
With
ethanol; sodium ethanolate; hydrazine hydrate;
at 200 - 210 ℃;
DOI:10.1021/ja01260a027
- Guidance literature:
-
Multi-step reaction with 4 steps
1: copper oxide-chromium oxide / 235 - 250 °C / 119888 Torr / Hydrogenation
2: ueber das Saeurechlorid
3: PCl5; toluene / Behandeln des Reaktionsprodukts mit SnCl2 und HCl in Aether bei 0grad und Erhitzen der erhaltenen orangeroten Krystalle mit wss. HCl
4: aqueous hydrazine; sodium ethylate; ethanol / 200 - 210 °C
With
ethanol; copper oxide-chromium oxide; phosphorus pentachloride; sodium ethanolate; hydrazine hydrate; toluene;
DOI:10.1021/ja01260a027