2,2,3,3,4,4,5,5-Octafluoropentyl acrylate

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5-Octafluoropentyl acrylate
• CAS No.: 376-84-1
• Deprecated CAS: 88007-50-5
• Molecular Formula: C8H6 F8 O2
• Molecular Weight: 286.122
• Hs Code.: 29161290
• European Community (EC) Number: 206-816-5
• DSSTox Substance ID: DTXSID5075236
• Nikkaji Number: J213.593K
• Wikidata: Q72497144
• Mol file: 376-84-1.mol

Synonyms:376-84-1;1H,1H,5H-Octafluoropentyl acrylate;2,2,3,3,4,4,5,5-Octafluoropentyl acrylate;2,2,3,3,4,4,5,5-octafluoropentyl prop-2-enoate;C8H6F8O2;2-Propenoic acid, 2,2,3,3,4,4,5,5-octafluoropentyl ester;2,2,3,3,4,4,5,5-Octafluoropentylacrylate;1h,1h,5h-perfluoropentyl acrylate;EINECS 206-816-5;1H,1H,5H-Octafluoropentyl Acrylate (stabilized with MEHQ);Acrylic Acid 1H,1H,5H-Octafluoropentyl Ester;SCHEMBL37167;DTXSID5075236;WISUNKZXQSKYMR-UHFFFAOYSA-;C8-H6-F8-O2;MFCD00039279;AKOS015915340;BS-43787;LS-192524;CS-0121493;FT-0609069;O0318;1H,1H,5H-Octafluoropentyl Acrylate, >/=97%;acrylic acid 1H,1H,5H-octafluoro-pentyl ester;D91861;Acrylic acid=2,2,3,3,4,4,5,5-octafluoropentyl ester;1H,1H,5H-Octafluoropentyl Acrylate, (stabilized with MEHQ);1H,1H,5H-Octafluoropentyl acrylate, stab. with 30-50ppm 4-methoxyphenol;2,2,3,3,4,4,5,5-Octafluoropentyl acrylate, 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

Chemical Property of 2,2,3,3,4,4,5,5-Octafluoropentyl acrylate

Chemical Property:

• Appearance/Colour: colorless liquid
• Refractive Index: n20/D 1.349(lit.)
• Boiling Point: 122 °C140 mm Hg(lit.)
• Flash Point: 72 ºC
• PSA: 26.30000
• Density: 1.488
• LogP: 2.88660
• Storage Temp.: Keep Cold
• Water Solubility.: Practically insoluble in water
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 7
• Exact Mass: 286.02400473
• Heavy Atom Count: 18
• Complexity: 325

Purity/Quality:

99% ^*data from raw suppliers

1H,1H,5H-Octafluoropentyl Acrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,N,F
• Statements: 36/37/38-51/53
• Safety Statements: 26-28-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC(=O)OCC(C(C(C(F)F)(F)F)(F)F)(F)F

Technology Process of 2,2,3,3,4,4,5,5-Octafluoropentyl acrylate

There total 4 articles about 2,2,3,3,4,4,5,5-Octafluoropentyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

potassium acrylate (10192-85-5) + 5-[(chlorosulfinyl)oxy]-1,1,2,2,3,3,4,4-octafluoropentane (254756-55-3) → acrylate de trihydro-1,1,5 octafluoropentyle (376-84-1)

Guidance literature:

DOI:10.1023/A:1020788902312

Reference yield: 38.5%

2,2,3,3,4,4,5,5-octafluoropentan-1-ol (355-80-6) + acrylic acid (79-10-7) → acrylate de trihydro-1,1,5 octafluoropentyle (376-84-1)

Guidance literature:

With hydroquinone; sulfonated coal; sulfuric acid; In toluene; at 100 ℃;

Reference yield:

2,2,3,3,4,4,5,5-octafluoro-pentan-1-ol; compound with triethyl-amine → acrylate de trihydro-1,1,5 octafluoropentyle (376-84-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / SOCl₂ / CHCl₃ / -40 - 20 °C

With thionyl chloride; In chloroform;

DOI:10.1023/A:1020788902312

upstream raw materials:

2,2,3,3,4,4,5,5-octafluoropentan-1-ol

acrylic acid

acryloyl chloride

potassium acrylate

Downstream raw materials:

dimethyl(tridecyl)benzylammonium salt of 1H,1H,5H-octafluoropentyl sulfopropionate

Refernces

• 1、 Boutevin,Rigal,Rousseau,Bosc. "-". . p. 47 - 73. Retrieved 2007/10/02.
• 2、 Gol'din, G. S.,Averbakh, K. O.,Nekrasova, L. A.. "ORGANOFLUORINE DERIVATIVES OF SALTS OF SULFOCARBOXYLATE ESTERS". . p. 1463 - 1467. Retrieved 2007/10/02.