3-Hydroxy-2,2-dimethylpropyl methacrylate

Base Information

• Chemical Name: 3-Hydroxy-2,2-dimethylpropyl methacrylate
• CAS No.: 13463-71-3
• Molecular Formula: C9H16 O3
• Molecular Weight: 172.224
• European Community (EC) Number: 236-676-0
• DSSTox Substance ID: DTXSID00158838
• Nikkaji Number: J25.104F
• Wikidata: Q83027147
• Mol file: 13463-71-3.mol

Synonyms:3-Hydroxy-2,2-dimethylpropyl methacrylate;13463-71-3;EINECS 236-676-0;(3-hydroxy-2,2-dimethylpropyl) 2-methylprop-2-enoate;SCHEMBL27278;DTXSID00158838;Methacrylic acid 3-hydroxy-2,2-dimethylpropyl ester

Chemical Property of 3-Hydroxy-2,2-dimethylpropyl methacrylate

Chemical Property:

• Vapor Pressure: 0.00169mmHg at 25°C
• Boiling Point: 261.1°Cat760mmHg
• Flash Point: 104.1°C
• PSA: 46.53000
• Density: 0.995g/cm³
• LogP: 1.12420
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 172.109944368
• Heavy Atom Count: 12
• Complexity: 182

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(C)(C)CO

Technology Process of 3-Hydroxy-2,2-dimethylpropyl methacrylate

There total 6 articles about 3-Hydroxy-2,2-dimethylpropyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

→ 3-hydroxy-2,2-dimethylpropyl methacrylate (13463-71-3) + neopentyl glycol dimethacrylate (1985-51-9)

Guidance literature:

Reference yield:

2,2-Dimethyl-1,3-propanediol (126-30-7) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 3-hydroxy-2,2-dimethylpropyl methacrylate (13463-71-3) + neopentyl glycol dimethacrylate (1985-51-9)

Guidance literature:

With methanol; sodium methylate;

Reference yield:

hexahydro-2H-oxepin-2-one (502-44-3,24980-41-4,80137-66-2) → 3-hydroxy-2,2-dimethylpropyl methacrylate (13463-71-3)

Guidance literature:

With hydrogenchloride; n-butyllithium; In tetrahydrofuran; hexane;

upstream raw materials:

2,2-Dimethyl-1,3-propanediol

methacrylic acid methyl ester

hexahydro-2H-oxepin-2-one

3-(methacryloyloxy)-2,2-dimethylpropyl 3-oxobutanoate

Refernces

• 1、 Popescu, Dragos,Hoogenboom, Richard,Keul, Helmut,Moeller, Martin. "Hydroxy functional acrylate and methacrylate monomers prepared via lipase-catalyzed transacylation reactions". experimental part. p. 80 - 89. Retrieved 2010/08/20.
• 2、 -. "Chromene compound". . . Retrieved 2008/06/13.