CADMIUM RHODANIDE

Base Information

• Chemical Name: CADMIUM RHODANIDE
• CAS No.: 865-38-3
• Molecular Formula: C2CdN2S2
• Molecular Weight: 228.577
• Mol file: 865-38-3.mol

Synonyms:Cadmiumthiocyanate (6CI,7CI);Cadmium dithiocyanate;Cadmium thiocyanate (Cd(SCN)2);Cadmium, bis(thiocyanato-S)-;Cadmium, bis(thiocyanato-S)-,homopolymer;Cadmium, bis(thiocyanato-kS)-;

Chemical Property of CADMIUM RHODANIDE

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Boiling Point: 146°C at 760 mmHg
• Flash Point: 42.1°C
• PSA: 98.18000
• LogP: 1.32746

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CADMIUM RHODANIDE

There total 39 articles about CADMIUM RHODANIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cadmium(II) nitrate tetrhydrate + potassium thioacyanate (333-20-0) → cadmium(II) thiocyanate (865-38-3)

Guidance literature:

In ethanol; according standard method: Ramakrishna, R.S and Thuraisingham R., J.Inorg.Nuc.Chem., 35, 285, (1973); filtn., concn.;

Reference yield:

cadmium(II) sulfate*8/3H2O + barium thiocyanate trihydrate (5908-82-7,68016-36-4) → cadmium(II) thiocyanate (865-38-3)

Guidance literature:

In water;

DOI:10.1002/zaac.201200268 DOI:10.1002/zaac.201200479 DOI:10.1002/zaac.201400494 DOI:10.1002/zaac.201700250

Reference yield:

cadmium sulfate + barium thiocyanate (2092-17-3) → cadmium(II) thiocyanate (865-38-3)

Guidance literature:

In water; byproducts: BaSO4; hot aq. soln. of Ba(SCN)2 was added dropwise to hot aq. soln. of CdSO4; filtered off, filtrate was evapd., recrystd. from EtOH;

DOI:10.1021/ic50225a064

upstream raw materials:

Thiocyanate

cadmium(II)

cadmium(II) monothiocyanate

barium thiocyanate

Downstream raw materials:

bis(1,10-phenanthroline N,N'-dioxide)dithiocyanatocadmium

(benzil phenylhydrazone)(thiocyanato)2 cadmium(II)

Refernces

• 1、 Jochim, Aleksej,Jess, Inke,N?ther, Christian. "Structural diversity in Cd(NCS)2-3-cyanopyridine coordination compounds: Synthesis, crystal structures and thermal properties". . p. 163 - 172. Retrieved 2020.
• 2、 Cannas, Mario,Carta, Gino,Cristini, Alessandro,Marongiu, Giaime. "". . . Retrieved 1976.
• 3、 Wang, Xin Qiang,Yu, Wen Tao,Xu, Dong,Lu, Meng Kai,Yuan, Duo Rong. "catena-poly[[bis(thiocyanato-κN)-cadmium(II)]-di-μ-thiourea- κ4S:S]". . p. m336-m337. Retrieved 2002.
• 4、 Woehlert, Susanne,Peters, Lars,Naether, Christian. "Synthesis, structures and magnetic properties of Fe(ii) and Co(ii) thiocyanato coordination compounds: On the importance of the diamagnetic counterparts for structure determination". . p. 10746 - 10758. Retrieved 2013.
• 5、 Jess, Inke,Boeckmann, Jan,Naether, Christian. "New cadmium thio- and selenocyanato coordination compounds: Structural snapshots on the reaction pathway to more condensed anionic networks". . p. 228 - 236. Retrieved 2012.
• 6、 Boeckmann, Jan,Jess, Inke,Reinert, Thorben,Naether, Christian. "New Cd thio- and selenocyanato coordination compounds and their impact on the structures and reactivity of their paramagnetic counterparts". . p. 5502 - 5511. Retrieved 2011.
• 7、 Neumann, Tristan,Jess, Inke,dos Santos Cunha, Cesar,Terraschke, Huayna,N?ther, Christian. "Luminescent Zn(NCS)2 and Cd(NCS)2 coordination compounds with pyridine derivatives: Synthesis, structures and physical properties". . p. 15 - 24. Retrieved 2018/04/05.
• 8、 Neumann, Tristan,Germann, Luzia S.,Moudrakovski, Igor,Dinnebier, Robert E.,dos Santos Cunha, Cesar,Terraschke, Huayna,N?ther, Christian. "Synthesis, Crystal Structures, and Properties of M(NCS)2-3-aminomethylpyridine Coordination Compounds (M = Cd, Zn)". . p. 1904 - 1912. Retrieved 2017/10/07.